Structure and Mössbauer study of La1−xCa_xFeO3−δ perovskite

In this paper, La[Formula: see text]Ca x FeO 3 ([Formula: see text], 0.1, 0.2, 0.3, 0.4, 0.5) perovskite samples were synthesized by sol–gel method. X-ray diffraction (XRD), transmission electron microscopy (TEM) and Mössbauer were used for measuring. XRD measurement shows that the unit cell volume of LaFeO 3 gradually decreases with increasing Ca content. The morphology of the sample was observed by TEM, and there were significant changes in volume and size of the samples with different calcium contents. Mössbauer spectrum study found that with the gradual increase of Ca content, Fe[Formula: see text] and Fe[Formula: see text] were formed in the sample. The study in this paper will provide a reference for future research on the effect of different calcium contents on the electronic structure of lanthanide ferrite.