Two-dimensional layered In2P3S9: A novel superior anode material for sodium-ion batteries
JOURNAL OF ENERGY CHEMISTRY(2024)
摘要
Developing reliable and efficient anode materials is essential for the successfully practical application of sodium-ion batteries. Herein, employing a straightforward and rapid chemical vapor deposition technique, two-dimensional layered ternary indium phosphorus sulfide (In2P3S9) nanosheets are prepared. The layered structure and ternary composition of the In2P3S9 electrode result in impressive electrochemical performance, including a high reversible capacity of 704 mA h g-1 at 0.1 A g-1, an outstanding rate capability with 425 mA h g-1 at 5 A g-1, and an exceptional cycling stability with a capacity retention of 88% after 350 cycles at 1 A g-1. Furthermore, sodium-ion full cell also affords a high capacity of 308 and 114 mA h g-1 at 0.1 and 5 A g-1. Ex-situ X-ray diffraction and ex-situ high-resolution transmission electron microscopy tests are conducted to investigate the underlying Na-storage mechanism of In2P3S9. The results reveal that during the first cycle, the P-S bond is broken to form the elemental P and In2S3, collectively contributing to a remarkably high reversible specific capacity. The excellent electrochemical energy storage results corroborate the practical application potential of In2P3S9 for sodium-ion batteries.(c) 2023 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press. All rights reserved.
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关键词
Metal thiophosphate,Anode material,Sodium-ion battery,Full cell
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