Effect of β-cyclodextrin on the CO release kinetics and antimicrobial activity of [NEt4][Mo(CO)5Br]

Rodrigo P. Monteiro,Isabel B. Calhau,Ana C. Gomes,Carla Pereira,Cátia Vieira,M. Amparo F． Faustino,Adelaide Almeida,Martyn Pillinger,Carlos C. Romão,Isabel S. Gonçalves

Journal of Organometallic Chemistry（2023）

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摘要

•β-cyclodextrin (CD) and [Et4N][Mo(CO)5Br] (1) were coground in a planetary ball mill.•The CD component in the 1-βCD solid dispersion improves the aqueous solubility of 1.•Hydrolysis-induced CO release from 1 and 1-βCD was compared via the myoglobin assay.•βCD increases the half-life of CO release from 1, while decreasing the efficiency.•The bactericidal activity of 1 against E. coli cells was retained in the 1-βCD product.

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关键词

Carbon monoxide-releasing molecules,β-cyclodextrin,Mb assay,Antibacterial activity,Escherichia coli

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