Pulsation effects on mixing behaviour of binary particles with different densities in supercritical water fluidized bed reactors: A CFD-DEM study

A coupled computational fluid dynamics - discrete element method (CFD-DEM) model for simulating supercritical water fluidized bed reactors (SCWFBR) is established and verified using the previous correlations based on experimental data. The CFD-DEM model is then adopted to investigate the pulsation effects on the mixing behaviour of binary particles with different densities in the SCWFBR. Numerical results show that external energy pulses can be effective in promoting the mixing of binary particle systems with different densities in SCWFBR which cannot be achieved by simply increasing the flow rate constantly. Within the current parameter range: low-frequency pulses are favored to promote particle mixing rather than high-frequency pulses, and an optimal frequency exists. The role of low amplitudes in influencing mixing degree is slight, but the particle mixing degree can be greatly enhanced by increasing the pulse amplitude beyond a certain value. The mechanism that pulsed inlet fluid promotes particle mixing is to raise the heavy particles which are inclined to stay at low positions during the fluidization. The Fast Fourier Transform (FFT) method to predict the optimal frequency established for size-induced segregation can be applicable to solve the problem of the density-induced segregation.