An 'active Site Anchoring' Strategy for the Preparation of PBO Fiber Derived Carbon Catalyst Towards an Efficient Oxygen Reduction Reaction and Zinc-Air Batteries.

In order to promote the wide application of clean energy-fuel cells, it is urgent to develop transition metal-based high-efficiency oxygen reduction reaction (ORR) catalytic materials with a low cost and available rich raw material resources to replace the currently used precious metal platinum-based catalytic materials. Herein, a novel 'active-site-anchoring' strategy was developed to synthesize highly-activated carbon-based ORR catalysts. Firstly, poly(p-phenylene benzobisoxazole) (PBO) fiber with a stable chemical structure was selected as the main precursor, and iron was complexed on its surface, and then poly-dopamine (PDA) was coated on the surface of PBO-Fe to form a PBO-Fe-PDA composite structure. Therefore, carbon-based catalyst PBO-Fe-PDA-900 with abundant Fe2O3 active sites was prepared by anchoring iron sites by PDA after pyrolysis. As a result, the PBO-Fe-PDA-900 catalyst displayed a 30 mV higher half-wave potential (0.86 V) than that of a commercial Pt/C electrocatalyst. Finally, PBO-Fe-PDA-900 was used as a cathode material for zinc-air batteries, showing a high peak power density superior to Pt/C. This work offers new prospects for the design of efficient, non-precious metal-based materials in zinc-air batteries. The PBO-Fe-PDA-900 electrocatalyst developed from PDA protected Fe modified PBO fibers displays an overall superior electrocatalytic activity for the ORR and zinc-air batteries.