A novel sustainable separation process based on special azeotropic behavior of benzene/ethanol/butanone: Process design and multi-performance evaluation

Special azeotropic behaviors of complex mixtures can be used to develop distillation processes to realize energysaving separation. Based on the residual curves of the system at different pressures and an examination of the impact of several extractants on the relative volatility, the pressure-swing distillation (PSD) process and the extractive distillation (ED) process were proposed to separate benzene/ethanol/butanone azeotrope. According to the characteristic of the azeotropic disappearance of ethanol/butanone with increasing pressure, two new extractive pressure-swing distillation (EPSD) processes were developed and compared with PSD as well as ED. To be able to determine the optimal operating parameters for various processes, the non-dominated sorting genetic algorithm II (NSGA-II) was utilized. Heat integration was designed for the EPSD processes to reduce energy consumption. The above processes were evaluated in four aspects of the economy, energy, environment and exergy. The relationship between the four performances of different processes and the normal distance was discussed. The results indicate that the EPSD processes show better performance than the ED and PSD processes. Compared with the two EPSD processes, the total annual cost (TAC) of the heat integrated EPSD processes (HIEPSD) was reduced by 13.2% and 14.4%, the total gas emissions of CO2, SO2 and NOX were also reduced by 23.6% and 27.2%, respectively. Hence, coupling the ED process with the PSD process and heat integration can both better improve the separation performance of distillation.