Influence of elevated temperature on waste concrete powder and its application in alkali activated materials

Concrete has been a common building material widely used for decades to build the infrastructure. As a results, considerable amount of waste concrete is produced which is hazardous to the environment. At present, recycling waste concrete is limited to the aggregates for non-structural applications. The low reactivity of waste concrete powder (WCP) limits its use as a binder. Therefore, this study is conducted to enhance the reactivity of WCP to increase its viability as an alkali activated binder. The study was conducted in two phases. In Phase I, the WCP was thermally treated at temperatures ranging between 600 degrees C and 800 degrees C and the impact of this calcination on the physiochemical characteristics of thermally treated waste concrete powder (TWCP) was studied. The phase transformation after calcination was analyzed by observing the properties of WCP and TWCP using scanning electron microscope (SEM), X-ray diffractometer (XRD), Fourier transformed infrared spectroscopy (FT-IR) and thermogravimetric analysis (TGA) techniques. The physical changes were also studied by comparing the density, specific surface area and particle size distribution in WCP and TWCP. It was found that the thermal treatment of WCP resulted in the decomposition of several phases along with a change in quartz structure. Also with temperature increase, the increase in density and particles fineness was observed, which was significant when thermal treatment was performed at 800 degrees C. The alkali activated WCP and TWCP was prepared to explore the microstructure and strength. The reactivity and strength of TWCP was superior to that of WCP. However, the highest strength obtained after alkali activation of TWCP was less than 10 MPa which is not optimal for a primary binder. Therefore, in Phase II of this study, the performance of TWCP in a binary cement-based mortar was explored by blending it with 0-50 wt% ground granulated blast furnace slag (GGBS) and the series of experiments including compressive strength, flexural strength and drying shrinkage was carried out to characterize the properties of composites. The superior strength and improved drying shrinkage obtained by mortars comprising TWCP-800 were due to the combination of filler effects and increased reactivity. No significant change in the properties of mortar containing 10 wt% TWCP-800 was observed. Study reveals that the thermal treatment of WCP at 800 degrees C is optimal and a sustainable approach to producing a supplementary binder for alkali activated materials.