Presentation and Performance of a Planar Solid Oxide Fuel Cell with Chaotic Gas Channels

Flow condition in gas channels determines the distribution and diffusion of reactants, governing electrochemical reactions in the solid oxide fuel cell (SOFC). It is found that the magnitude and direction of fluid velocity change with the geometric position in the channel, which leads to larger secondary flow velocity components and enhances mass transfer between fluids. Laser Doppler velocimetry experiment is conducted to verify the accuracy of numerical results of fluid flow in chaotic flow channels. Herein, a 3D numerical model with coupled multiphysics fields is built to evaluate fluid flow in channels and SOFC performance. The distribution characteristics of reactants in chaotic flow channel and the characteristics of temperature distribution, current density and power density in SOFCs caused by structures of straight and chaotic flow channels are analyzed and discussed. Compared with conventional straight flow channel SOFCs, the average current density of SOFC with chaotic flow channel is improved and the power density is increased by 9.7%. The reactant homogeneity in the electrode is also improved, which reduces the concentration polarization loss of SOFC. A planar solid oxide fuel cell (SOFC) with chaotic gas channels is proposed. The distribution characteristics of reactants in the chaotic flow channel are analyzed and compared to those in the conventional straight channel. The chaotic advection in the gas channels of SOFC enhances significantly the transfer and diffusion of the reactants from the flow channels to the porous electrode.image (c) 2023 WILEY-VCH GmbH