Noncovalent interaction network of chalcogen, halogen and hydrogen bonds for supramolecular β-sheet organization.
Chemical communications (Cambridge, England)(2024)
摘要
An alanine-based bilateral building block, linked by 2,5-thiophenediamide motifs and equipped with C-terminal 4-iodoaniline groups, was designed, allowing a noncovalent interaction network consisting of intramolecular chalcogen bonds and intermolecular halogen/hydrogen bonds, which cooperatively maintain a supramolecular β-sheet organization in the solid state, as well as in dilute CH3CN solution with a high g factor of -0.017.
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