Development of the Sb4O5Cl2@NbSe2 Composite: The Impact of 2H-NbSe2 Nanoparticles on Sb4O5Cl2 and Their Application for the Removal of Cr(VI)/Fe(III) and Methyl Orange from Wastewater.

A potential adsorbent, Sb4O5Cl2@NbSe2 composite, was generated from the Sb4O5Cl2 photocatalyst and 5 wt % layered 2H-NbSe2 nanoparticles for the highly effective removal of Cr(VI) and Fe(III) ions and methyl orange (MO) from aqueous solution, and a comparison was drawn against the precursors. Sb4O5Cl2 crystallites and NbSe2 nanoparticles were synthesized hydrothermally, and the composite was prepared by the incipient wetness impregnation technique. The crystal structure of Sb4O5Cl2 was determined by single-crystal X-ray diffraction (SCXRD) data. Powder X-ray diffraction (PXRD) study revealed the 2H phase of NbSe2 nanoparticles. Field emission scanning electron microscopy (FESEM) analysis confirmed the formation of the spherical-shaped NbSe2 nanoparticles from rod-shaped bulk 2H-NbSe2. Morphological changes from the hexagonal to irregular prismatic shape were found upon the formation of the Sb4O5Cl2@NbSe2 composite compared to pure Sb4O5Cl2. Negative ζ-potential values indicated that electrostatic interactions were the predominant factor for the adsorption process. Sb4O5Cl2@NbSe2 provided removal efficiencies of 99% for MO in 6 h, 96.52% for Cr(VI) within 2.5 h, and 92.43% for Fe(III) within 4 h of 10 mg/L initial concentration. The maximum adsorption capacities of the composite for MO, Fe(III), and Cr(VI) were found to be 66.56, 131.48, and 122.30 mg/g, respectively, as calculated using the Langmuir isotherm equation.