Ultrafast and Durable Sodium-Ion Storage of Pseudocapacitive VN@C Hybrid Nanorods from Metal-Organic Framework

Vanadium nitride (VN) is a promising electrode material for sodium-ion storage due to its multivalent states and high electrical conductivity. However, its electrochemical performance has not been fully explored and the storage mechanism remains to be clarified up to date. Here, the possibility of VN/carbon hybrid nanorods synthesized from a metal-organic framework for ultrafast and durable sodium-ion storage is demonstrated. The VN/carbon electrode delivers a high specific capacity (352 mA h g-1), fast-charging capability (within 47.5 s), and ultralong cycling stability (10 000 cycles) for sodium-ion storage. In situ XRD characterization and density functional theory (DFT) calculations reveal that surface-redox reactions at vanadium sites are the dominant sodium-ion storage mechanism. An energy-power balanced hybrid capacitor device is verified by assembling the VN/carbon anode and active carbon cathode, and it shows a maximum energy density of 103 Wh kg-1 at a power density of 113 W kg-1. A well-defined VN@C hybrid is synthesized by a pre-stabilization strategy from a metal-organic framework (MOF) precursor. Nano-engineering of VN and hybridizing with conductive carbon network expose abundant active sites on/near the surface, while the tight component connection inherited from MOF enables the structural stability, which corporately boosts the rapid surface-redox pseudocapacitive reaction for ultrafast and durable Na+ storage. image