Expanding Luminescence Horizons in Macropolyhedral Heteroboranes

Luminescence is observed in three novel macropolyhedral nineteen- and eighteen-vertex chalcogenaboranes: Se2B17H17 (1), SeB17H19 (3) and SeB18H20 (4). This led us to the recognition that previously published macropolyhedral heteroborane species might also exhibit luminescence. Thus, the known nineteen- and eighteen-vertex dithiaboranes S2B17H17 (2), n-S2B16H16 (5) and i-S2B16H16 (6) were synthesised and also found to exhibit a range of luminescent properties. These macropolyhedral species are very different from the previously unique fluorescent binary borane B18H22 in terms of their structural architectures, by the presence of borane cluster hetero atoms, and, as in the cases of 5 and 6, that their synthetic origins are not derived simply through the modification of B18H22 itself. They consequently greatly expand the possibilities of finding new luminescent inorganic borane species. An investigation of the new 18- and 19-vertex macropolyhedral heteroborane clusters reported here containing sulphur and selenium cluster vertices and a subsequent reinvestigation of analogous known species has revealed that the property of luminescence in this wide range of structural types is much more extensive than previously recognised, where it has been restricted to those of the binary borane anti-B18H22 and its derivatives. image