Synthesis, Structure, and Properties of 4-Methyl-n-[2-(pentafluorophenyliminomethyl)phenyl]methyl-benzenesulfamide and the Copper(II) Complex Based on It
Journal of Structural Chemistry(2024)
摘要
A new azomethine compound 4-methyl-N-[2-pentafluorophenyliminomethyl)phenyl]methylbenzenesulfamide and a Cu(II) complex based on it are obtained and characterized by 1H NMR, IR spectroscopy and the elemental analysis. Crystal structures of azomethine and its complex are analyzed by single crystal X-ray diffraction (XRD). From the single crystal XRD data it is found that the Cu(II) complex crystallizes in the triclinic space group P1̅ . The unit cell contains two crystallographically independent mononuclear molecules with similar geometries. In the complex, copper ions have a distorted tetrahedral environment of four nitrogen atoms, which is formed by two bidentate coordinated azomethine ligands. From magnetic measurements it is found that the Cu(II) complex is paramagnetic.
更多查看译文
关键词
Schiff base,ligand,copper(II) chelate,single crystal XRD.
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要