Multi-phase behavior and pore-scale flow in medium-high maturity continental shale reservoirs with Oil, CO2, and water

The application of CO2 to enhancing the recovery of continental shale oil has attracted considerable attention. However, the introduction of CO2 leads to intricate phase behavior and flow mechanisms. In this study, firstly, a three-phase equilibrium model is developed, with nano-confinement effects taken into consideration, to analyze the phase behavior of continental shale oil-CO2-water systems in both a bulk phase and nanopores. Building upon this, an improved pore network model is introduced to simulate steady-state oil-water flow while considering the alterations in fluid properties resulting from CO2 dissolution. The findings reveal that with the increase of CO2 injection, a transition from two phases of liquid and water to two phases of vapor and water, three phases of liquid, vapor and water, two phases of vapor and water, and ultimately a pure vapor phase occurs. The dissolution of CO2 exerts a pronounced impact on the composition and properties of the oil phase, and the viscosity and interfacial tension reduction effects play a central role in affecting the flow capacity. Nano-confinement effects facilitate the transfer of vapor-phase molecules into the water and oil phases, thus increasing the concentration of CO2 in the oil and water phases. The pore-scale flow results reveal that upon injection, water quickly traverses the larger pores. More smaller pores become accessible after CO2 dissolution, significantly boosting the extraction of shale oil from these smaller pores and slightly reducing the water output.