Radiating biofuel-blended turbulent nonpremixed hydrogen flames on a coaxial spray burner

The low radiant intensity and luminosity of hydrogen flames can be enhanced by the addition of a small portion of sooting biofuels. To achieve higher effectiveness, the impact of blending turbulent nonpremixed hydrogen flames with liquid biofuels, by gas -assist atomisation, is investigated and compared with the introduction methods of prevapourisation and ultrasonic spray. The flame appearance, luminosity, radiant fraction, centreline temperature, and the near -field spray characteristics of four biofuel surrogates (eucalyptol, D-limonene, guaiacol, and anisole) blended into hydrogen flames are measured experimentally. Radiating biofuel/hydrogen flames are achieved on a coaxial needle spray burner by the addition of 0.1-0.3 mol% biofuel surrogates. Compared with the unblended hydrogen flame, the luminosity and radiant fraction are enhanced by 30%-500% and 2%-15%, respectively, with the addition of biofuel surrogates. The results show that adding the biofuel surrogates by gas -assist atomisation is more effective than prevapourisation and ultrasonic atomisation in luminosity and radiant fraction enhancement. It is found that the local fuel -rich conditions, which are beneficial for soot formation, are further facilitated by the larger droplets and spray objects generated by gas -assist atomisation. Of the additives tested, anisole is the most effective for luminosity and radiant fraction enhancement of a hydrogen flame while exhibiting the largest flame temperature drop due to the enthalpy of vapourisation and the radiative loss from the promoted soot formation. The viscosity and surface tension greatly influence the spray characteristics which in turn impacts the flame characteristics. Guaiacol, the representative of lignin, appears to have the lowest effectiveness in radiant fraction enhancement due to the presence of a hydroxy group, a higher bond dissociation enthalpy, and a coarser spray ascribed to higher viscosity and surface tension.