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Lignin-Based Polymer Networks Enabled N, S Co-Doped Defect-Rich Hierarchically Porous Carbon Anode for Long-Cycle Li-Ion Batteries

ACS sustainable chemistry & engineering(2024)SCI 2区

Dalian Polytech Univ | Zhejiang Normal Univ

Cited 0|Views23
Abstract
The commercial graphitic anode with low specific capacity and serious lithium dendrite growth has limited further improvements of Li-ion batteries (LIBs). Here, we report a hierarchical porous hard carbon with N, S codoping (LSCF) that is synthesized using trifunctional sodium lignosulfonate (LS) from the pulp waste as the self-sacrificing template, carbon source, sulfur source, and natural chitosan as both the carbon source and nitrogen source. The strong hydrogen-bond interaction between the LS and chitosan enabled the robust stability of the carbon framework. And the self-template of sulfates and carbonates from LS enabled the formation of the hierarchical porous structure. First-principles calculations indicate that the hierarchical porous LSCF carbon with heteroatom doping has a lower diffusion barrier of Li+ and a higher electron conductivity. As an anode for LIBs, the LSCF delivers the specific capacity of 350 mAh g(-1) at 100 mA g(-1) with 85% retention after 1000 cycles. This work offers a one-step and low-cost method to fabricate the porous hard carbon anode for LIBs with dual-atom doping based on green natural polymers.
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lignin,chitosan,doping,hard carbonanode,lithium-ion battery
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要点】:本研究开发了一种基于木质素衍生物的聚合物网络,通过一种简便的绿色合成方法,制备出同时掺杂氮和硫的缺陷丰富 hierarchically 多孔碳负极,显著提高了锂离子电池的循环性能和稳定性。

方法】:采用自牺牲模板法,利用来自造纸废料的三功能木质素磺酸钠(LS)和天然壳聚糖作为碳源和氮源,通过调控氢键相互作用和自模板的硫酸盐及碳酸盐,形成稳定的多孔碳框架。

实验】:通过实验,得到的氮硫共掺杂多孔硬碳(LSCF)在100 mA g(-1)的电流密度下,具有350 mAh g(-1)的比容量,并且在1000次循环后容量保持率为85%,展现出优异的循环稳定性。此工作提供了一种基于绿色天然高分子的,一步法制备双原子掺杂多孔硬碳负极的新方法,为锂离子电池的进一步发展提供了新思路。