Quartz chemico-structural characterization: a tool for sediment source tracing

Quartz is ubiquitous within continental crust and can virtually be found within all rock types (plutonic, metamorphic and sedimentary). During erosion, weathering and sedimentation processes, it has a very high preservation potential and is often used to trace sediments production and transport dynamics. The QUARTZ project (Multi-methods characterization of quartz for source-to-sink tracing in alluvial sediment and dosimetry approaches – French ANR) aims to use quartz as a tracer for sediment sourcing river dynamics by combining conventional characterization method such as Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS), Laser Induced Breakdown Spectroscopy (LIBS), and Cathodo-Luminescence (CL), with dosimetric methods, such as Electronic Spin Resonance (ESR) and Optically Stimulated Luminescence (OSL) which are more classically used for Quaternary sediment dating. To this end, one must define a robust quartz chemico-structural and dosimetric signature that can be compared from one sample to the other. We also aim to better understand ESR, OSL, and CL signals controlled by structural quartz defects. These can be either intrinsic (e.g. dislocations, missing/supplementary O or Si), or extrinsic (foreign atoms), each technique being more or less sensitive to these different defects. In this study, we apply this multi-method approach to the various bedrock lithologies of the Strengbach catchment (ca.40 km²) draining a low mountain range located in the easternmost France (Vosges). These are largely dominated by crystalline metamorphic and plutonic rocks, with secondary Triassic sandstones (Buntsandstein). Bedrock samples have been treated mechanically and chemically to extract quartz grains. These grains have been analyzed using ESR and OSL techniques and mounted on thick sections (100 µm) for CL, LA-ICP-MS, and LIBS analyses. 100-µm thick-sections were used to prevent quartz tearing apart under LA-ICP-MS laser beam. Quartz characterization was completed by the study of whole-rock bedrock thick sections, analyzed with CL, LA-ICP-MS and LIBS approaches. Preliminary results allow identifying specific quartz chemico-structural signatures not only depending on rock type (gneiss, granite, sandstone) but also on formation process (magmatic, recrystallized, metamorphic or sedimentary). Further comparison between quartz analysis in whole rock and in separated grains samples permit to assess the impact of the chemical treatment on the quartz signatures and to identify quartz populations likely to be more represented in the alluvial sediments produced by the different lithologies. Finally, ongoing analyses point out the complex contribution of trace elements to OSL, ESR and CL signals.