Gallium oxide particles encapsulated in carbon fiber serve as freestanding electrodes for lithium-ion batteries

Ionics(2024)

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摘要
As a potential electrode material for lithium-ion batteries, Ga2O3 has high theoretical specific capacity and low lithium storage potential. Still, the bulk expansion efficiency and poor reaction kinetics during the reaction process hinder performance improvement. This paper successfully synthesised the Ga2O3 NPs@CF composite electrode with network core–shell structure using the electrospinning method. Carbon coating effectively alleviates the volume expansion of Ga2O3 during the reaction process. The carbon fibre network structure provides more transport channels for ions, and the Ga2O3 NPs@CF composite electrode shows excellent performance. In the long cycle test, after 500 cycles of 0.5 A/g, the discharge capacity reached 611.04mAh/g, and the capacity retention was 99.8
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关键词
Gallium oxide,Electrospinning,High-performance anode,Free-standing electrode
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