Thermal conductivity enhancement and shape stability of composite phase change materials using MIL-101(Cr)-NH2/expanded graphite/multi-walled carbon nanotubes
Journal of Energy Storage(2024)
摘要
Low heat conductivity and leakage much restrict the effective use of phase changing materials (PCMs) in heat energy management. Here, an expanded graphite (EG)/ multi-walled carbon nanotube (MWCNT) / metal organic framework (MOF: MIL-101(Cr)-NH2) composite was developed to solve these issues. The porous MOF can avoid the loss of liquid paraffin wax (PW). The heat conductivity of composite PCMs (CPCMs) was improved using EG/MWCNT with a mass ratio of 4:1. The thermophysical properties, heat stability and chemical compatibility of CPCMs were comprehensively investigated. Results demonstrate the successful preparation of CPCMs without any chemical reaction. The MOF (35 %)/EG(4 %)/MWCNT(1 %)/PW(60 %) CPCM exhibits superior thermophysical properties and its melting enthalpy (74.59 J/g) is near the theoretical level after 500 heating/cooling cycles. It exhibits a 792 % increment in heat conductivity from pure PW.
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关键词
Composite phase change material,Metal organic framework,Thermal conductivity,Multi-walled carbon nanotube,Thermal energy management
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