Solid-State Transformations of Active Materials in the Pores of Sulfurized-Polyacrylonitrile Fiber Membranes via Nucleophilic Reactions for High-Loading and Free-Standing Lithium–Sulfur Battery Cathodes

Hao Liu,Yun Zhang, Yongbing Li,Na Han, Haihui Liu,Xingxiang Zhang

Advanced Fiber Materials（2024）

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摘要

Sulfurized polyacrylonitrile (SPAN) has emerged as an excellent cathode material for lithium–sulfur batteries (LiSBs), and it addresses the shuttle effect through a solid‒solid reaction. However, the actual sulfur loadings in SPAN often remain below 40 wt

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关键词

Lithium–sulfur batteries,Sulfurized polyacrylonitrile,Cathode–electrolyte interphase,High active material content,Nucleophilic reactions

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