Access to Carbamates and O-Aminobenzoates Via Oxidative Carbonylation of Amines with CO and Alcohols under Rhodium/copper Catalysis

Xiaoqi Chen, Xuyao Zhong,Lei Wang,Houyun Teng, Jingsheng Li, Shuai Chen,Rongjing Hu,Lei Yang

Organic chemistry frontiers（2024）

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摘要

Approaches to access carbamates and o-aminobenzoates via Rh/Cu catalytic system-enabled oxidative carbonylative reactions from amines, alcohols and CO have been demonstrated, featuring good functional group tolerance and a broad substrate scope.

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