AGA8 Supported Cu(I) Nanoclusters as In-situ Generated Cata-lysts for Room Temperature C-S Coupling Reactions in Water

Hao Jin, Yun Fan, Penghao Liu,Qi Meng,Qiaoqiao Teng

crossref(2024)

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摘要
A sustainable and green catalytic strategy for C-S coupling reactions is developed by combining micelle and transition metal catalysis. The synergistic AGA8@Cu(I) catalyst forms by spontaneous anchoring of the in-situ generated Cu(I) nanoclusters onto the AGA8 micelles, and has been fully characterized by XPS, FT-IR, and TEM. The catalyst is highly effective and recyclable in mediating the conversion of halides to disulfides in water at room temperature with a broad substrate scope.
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