Bendable, lamellar MXene membrane electrodes with diverse diffusion pathways for potential application in miniaturized capacitive deionization devices

Flexible devices have shown great application potential in portable and miniaturized devices. However, work on flexible electrodes for capacitive deionization (CDI) has not been well developed due to the issues of desalination property, processability, and availability under actual bending conditions. Herein, we constructed a kind of flexible lamellar MXene membrane by assembling Ti3C2Tx sheets with both crumpled and perforated structures and studied their desalination performance in conventional planar and bent configurations. The crumpled and perforated features in Ti3C2Tx (C-P-TC) nanosheets could optimize the in-plane and out-of-plane diffusion channels of the stacked samples, respectively, effectively improving the accessibility of membranes. As a result, the desalination performance of such C-P-TC electrodes was superior to that of those assembled from crumpled or perforated sheets alone. Significantly, this flexible C-P-TC electrode still showed excellent performance at real bend deformation, which possessed not only almost the same CDI capacity as the traditional planar configuration but also good cycling stability. This work not merely proposes an alternative strategy to improve the CDI performance of lamellar MXene electrodes by regulating the nanostructures of channels but also confirms their effective deionization ability under real bent state, greatly facilitating the potential use of flexible electrodes in miniaturized CDI devices.