Metal-Organic Frameworks-Derived Nanocarbon Materials and Nanometal Oxides for Photocatalytic Applications

Harnessing low-density solar energy and converting it into high-density chemical energy through photocatalysis has emerged as a promising avenue for the production of chemicals and remediation of environmental pollution, which contributes to alleviating the overreliance on fossil fuels. In recent years, metal-organic frameworks (MOFs) have gained widespread application in the field of photocatalysis due to their photostability, tunable structures, and responsiveness in the visible light range. However, most MOFs exhibit relatively low response to light, limiting their practical applications. MOFs-derived nanomaterials not only retain the inherent advantages of pristine MOFs but also show enhanced light adsorption and responsiveness. This review categorizes and summarizes MOFs-derived nanomaterials, including nanocarbons and nanometal oxides, providing representative examples for the synthetic strategies of each category. Subsequently, the recent research progress on MOFs-derived materials in photocatalytic applications are systematically introduced, specifically in the areas of photocatalytic water splitting to H2, photocatalytic CO2 reduction, and photocatalytic water treatment. The corresponding mechanisms involved in each photocatalytic reaction are elaborated in detail. Finally, the review discusses the challenges and further directions faced by MOFs-derived nanomaterials in the field of photocatalysis, highlighting their potential role in advancing sustainable energy production and environmental remediation. This review categorizes MOFs-derived nanomaterials, including nanocarbons and nanometal oxides. Subsequently, the recent research progress on MOFs-derived nanomaterials in photocatalytic water splitting for H2 production, photocatalytic CO2 reduction, and photocatalytic water treatment and their corresponding mechanisms are summarized. Finally, the challenges and further directions of MOFs-derived nanomaterials in photocatalytic reactions are proposed. image