Tailoring Two Magic Number Gold Nanoclusters Au₁₃ with N-Containing Diphosphine Ligands: Classical Icosahedral Core vs. Unprecedented UFO-Shaped Core

Jing Liu, Jia-Chuan Liu,Hai-Ling Wang,Pei-Yu Liao,Jian-Hua Jia,Ming-Liang Tong

Inorganic Chemistry Frontiers（2024）

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摘要

Two magic number Au13 nanoclusters, [Au13(PNP)5Cl2]Cl3 and [Au13(Hdppa)6]Cl5, with the same nuclearity number but completely distinct configurations, were elaborately constructed using N-containing diphosphine ligands (PNP or Hdppa). Significantly, the metal...

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Tailoring Two Magic Number Gold Nanoclusters Au13 with N-Containing Diphosphine Ligands: Classical Icosahedral Core vs. Unprecedented UFO-Shaped Core

Tailoring Two Magic Number Gold Nanoclusters Au₁₃ with N-Containing Diphosphine Ligands: Classical Icosahedral Core vs. Unprecedented UFO-Shaped Core