Modification of traditional composite nonwovens with stable storage of light absorption transients and photodynamic antibacterial effect

Combining photodynamic antimicrobials with nonwovens is prospective. However, common photosensitizers still have drawbacks such as poor photoactivity and the inability to charge. In this study, a photodynamic and high-efficiency antimicrobial protective material was prepared by grafting bis benzophenone-structured 4,4-terephthaloyl diphthalic anhydride (TDPA) photosensitizer, and antimicrobial agent chlorogenic acid (CA) onto spunbond-meltblown-spunbond (SMS) membranes. The charging rates for center dot OH and H2O2 were 6377.89 and 913.52 mu g/g/h. The light absorption transients structural storage remained above 69% for 1 month. High electrical capacity remained after seven cycles indicating its rechargeability and recyclability. The SMS/TDPA/CA membrane has excellent bactericidal performance when under illumination or lightless conditions, and the bactericidal efficiency of Escherichia coli and Staphylococcus aureus reached over 99%. The construction of self-disinfection textiles based on the photodynamic strategies proposed in this paper is constructive for expanding and promoting the application of textile materials in the medical field. The graphical abstract is intended to show that this study enabled SMS nonwovens to be successfully loaded with 4,4-terephthaloyl diphthalic anhydride and chlorogenic acid through two immersions, which led to the production of reactive oxygen species (ROS) and the killing of bacteria under light conditions. The section at the bottom left of the image is the cyclic generation mechanism of ROS.image