Triptycene-based diiron(II) mesocates: spin-crossover in solution.

Riccardo Mobili,Giovanni Preda,Daniele Dondi,Enrico Monzani,Dhanalakshmi Vadivel,Chiara Massera,Dario Pasini,Valeria Amendola

Chemical communications (Cambridge, England)（2024）

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摘要

Triptycene-based diiron(II) and dizinc(II) mesocates were obtained using a novel rigid ligand with two pyridylbenzimidazole chelating units fused into the triptycene scaffold. Studies on the diiron(II) assembly in solution showed that the complex undergoes thermal-induced one-step spin-crossover with T1/2 at 243 K (Evans method).

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