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    【要点】：本综述对聚氧金属酸鹽基宏環分子的最近进展进行了综述，包括其组装策略、晶体结构、性质和各种应用，并讨论了目前设计和构造聚氧金属酸鹽基宏環分子所面临的障碍和挑战。
    

    【方法】：综述
    

    【实验】：综述了聚氧金属酸鹽基宏環分子的组装策略、晶体结构、性质和各种应用，并讨论了目前设计和构造聚氧金属酸鹽基宏環分子所面临的障碍和挑战。