Polyoxometalate-based Macrocycles and Their Assembly

Xiao-Qi Ma,Hui-Ping Xiao,Yi Chen, Qian-Sheng Lai,Xin-Xiong Li,Shou-Tian Zheng

Coordination Chemistry Reviews（2024）

Fujian Provincial Key Laboratory of Advanced Inorganic Oxygenated-Materials

Cited 1|Views20

Abstract

Polyoxometalate (POM) macrocycles have been extensively investigated due to their potential applications in various fields, including sensing, optics, magnetism, proton conduction, catalysis, and host–guest chemistry, leveraging the advantages offered by their unique wheeled structures. In this review, the recent progress of POM macrocycles, including their assembly strategies, crystal structures, properties, and various applications, is reviewed. Additionally, the current obstacles and challenges regarding the design and construction of POM macrocycles are also discussed.

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Key words

Polyoxometalate,Macrocycles,Host-guest chemistry,Proton conduction,Gas separation

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