Iridium-Catalyzed Asymmetric Cascade Dearomative Allylation/Acyl Transfer Rearrangement: Access to Chiral N-Substituted 2-Pyridones

Wei-Yi Wang,Zhi-Yuan Yi, Zo-Fei Wang,Xiu-Qin Dong,Chun-Jiang Wang

Chemical Communications（2024）

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摘要

Iridium-catalyzed dearomative allylation/acyl transfer rearrangement has been developed with easily available 2-pyridinyl benzoates and vinyl ethylene carbonate. This protocol provided an expedient synthesis of a variety of chiral N-substituted 2-pyridones...

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