“Like binding a book”: Interfacial improvement of pre-melted ultrahigh molecular weight polyethylene by pulse vibration molding

Ultrahigh molecular weight polyethylene (UHMWPE) is widely used in industrial, military, and civilian applications owing to its excellent properties. However, the high entanglement degree of UHMWPE melt leads to great difficulties in diffusion and crystallization, which causes poor interfacial strength and mechanical properties of pre-melted UHMWPE, restricting its high-quality processing and high-value recycling. To this end, we propose a rapid interface stitching technology with a pulsed vibration force driving free volume homogenization and chain segment orientation. For the first time, pulse vibration molding (PVM) is applied for the hot-pressing of pre-melted UHMWPE, successfully realizing the interface stitching and product strengthening. Compared with those of the convention molding (CM) samples at 180 °C, the interfacial adhesive fracture toughness of the adhesive samples processed using PVM is increased by 105.9% and the work of tension of the recycled samples processed using PVM is also increased by 49.09%, respectively. The fracture strength of the PVM recycled samples at 180 °C reaches 91.77% of that of the pure samples and the yield strength is also higher, which significantly enhances the recycling of UHMWPE. The characterization results of the interfacial molecular chain entanglement and crystallization show that PVM strengthens the molecular chain diffusion and induces crystallization by promoting the orientation of chain segments, especially at the interface. Consequently, we believe that the proposed technology can play a significant role in the UHMWPE processing methods that involve surface healing.