Transformations of 5-hydrazinyl-1,2,4-triazines in the reaction with 2,5-norbornadiene

A. P. Krinochkin,A. Rammohan, D. S. Kopchuk,I. L. Nikonov,E. S. Starnovskaya, E. R. Sharafieva, I. S. Kovalev, G. V. Zyryanov,O. N. Chupakhin

Доклады Российской академии наук. Химия, науки о материалах（2023）

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摘要

The interaction between 5-hydrazinyl-substituted 1,2,4-triazines and 2,5-norbornadiene at elevated temperature and pressure (in autoclave) have been studied. The 2-aminopyridines, 5-amino-1,2,4-triazines and 6-unsubstituted pyridines are the products of this reaction. The formation of last two products depends on the substituent at C3 position of the triazine.

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