Extended Battery Compatibility Consideration from an Electrolyte Perspective

SMALL(2024)

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摘要
The performance of electrochemical batteries is intricately tied to the physicochemical environments established by their employed electrolytes. Traditional battery designs utilizing a single electrolyte often impose identical anodic and cathodic redox conditions, limiting the ability to optimize redox environments for both anode and cathode materials. Consequently, advancements in electrolyte technologies are pivotal for addressing these challenges and fostering the development of next-generation high-performance electrochemical batteries. This review categorizes perspectives on electrolyte technology into three key areas: additives engineering, comprehensive component analysis encompassing solvents and solutes, and the effects of concentration. By summarizing significant studies, the efficacy of electrolyte engineering is highlighted, and the review advocates for further exploration of optimized component combinations. This review primarily focuses on liquid electrolyte technologies, briefly touching upon solid-state electrolytes due to the former greater vulnerability to electrode and electrolyte interfacial effects. The ultimate goal is to generate increased awareness within the battery community regarding the holistic improvement of battery components through optimized combinations. Herein, an overview of pivotal research in electrolyte engineering is provided, highlighting their critical role in optimizing combinations of battery components and their compatibility. This optimization is key to improving battery performance. The objective is to foster a broader understanding of how strategic compatibility of battery components can lead to comprehensive enhancements in battery functionality. image
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关键词
electrode-electrolyte interphases,electrolyte engineering,energy storage applications,optimal battery component combinations,optimal redox conditions
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