Superior electrochemical performance of metal ligand framework-neodymium oxide composite for energy storage devices

Journal of Electroanalytical Chemistry(2024)

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摘要
Battery supercapacitor hybrids are gaining increasing importance in the realm of energy storage, driven by their exceptional electrochemical attributes, where the choice of electrode material emerges as a paramount factor for their efficacy. Here the enhancement in the electrochemical activity from the synergistic effect produced by combining copper benzene tetra carboxylate with neodymium oxide (Cu-1,3,5-BTC/Nd2O3) along with the individual samples Cu-1,3,5-BTC, and Nd2O3, is studied via various electrochemical measurements which includes CV, GCD and EIS in half cell assembly and for real-world applications in full cell assembly. The hybrid device achieved a specific capacity (Qs) of 390 C/g with an energy density (Es) of 91 W/kg and power density (Ps) of 5950 Wh/kg respectively. Theoretical approaches like linear and quadratic models were further employed and compared to scrutinize the CV curves and to deconvolute the capacitive and diffusive contribution.
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关键词
Batteries,Electrode materials,MOFs,Oxide,Supercapacitors,Hybrid supercapacitor
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