The importance of understanding (pre)catalyst activation in versatile C−H bond functionalisations catalysed by [Mn₂(CO)₁₀]

Jonathan B. Eastwood,Thomas J Burden,Lars Anders Hammarback, Chris S. Horbaczewskyj,Theo Tanner,Ian P Clark, Gregory M Greetham,Michael Towrie,Ian J. S. Fairlamb,Jason Martin Lynam

Chemical Science（2024）

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摘要

Mn-catalysed reactions offer great potential in synthetic organic and organometallic chemistry and the success of Mn carbonyl complexes as (pre)catalysts hinges on their stabilisation by strong field ligands enabling Mn(I)-based,...

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The importance of understanding (pre)catalyst activation in versatile C−H bond functionalisations catalysed by [Mn2(CO)10]

The importance of understanding (pre)catalyst activation in versatile C−H bond functionalisations catalysed by [Mn₂(CO)₁₀]