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Enhancing nitrate electroreduction for ammonia production over electron-deficient Co3O4 with La doping regulation

Science China Materials(2024)

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摘要
Electrocatalytic reduction of nitrate (NO3−) can efficiently transform NO3− into ammonia (NH3), enabling the simultaneous removal of NO3− pollutant from wastewater and the production of NH3. Here, we report the use of rare-earth lanthanum-doped Co3O4 nanowires array on carbon cloth (La-Co3O4/CC) as an efficient electrocatalyst for the conversion of NO3− to NH3. The as-synthesized La-Co3O4/CC demonstrates a remarkable NH3 Faradaic efficiency (96.36
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关键词
electrocatalytic NO3 − reduction,NH3 synthesis,La-Co3O4,Zn–NO3 − battery,density functional theory calculation
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