Mobility-induced kinetic effects in multicomponent mixtures
arxiv(2024)
摘要
We give an overview exploring the role of kinetics in multicomponent
mixtures. Compared to the most commonly studied binary (single species plus
solvent) case, multicomponent fluids show a rich interplay between kinetics and
thermodynamics due to the possibility of fractionation, interdiffusion of
mixture components and collective motion. This leads to a competition between
multiple timescales that change depending on the underlying kinetics. At high
densities, crowding effects are relevant and non-equilibrium structures can
become long-lived. We present the main approaches for the study of kinetic
effects in multicomponents mixtures, including the role of crowding, and
explore their consequences for equilibrium and non-equilibrium scenarios. We
conclude by identifying the main challenges in the field.
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