Diachronic evolvement from tetra-icosahedral to quasi-hexagonal close-packed bimetal clusters

Shisi Tang,Endong Wang, Yanzhen Wu, Tongxin Song,Meng Zhou,Xiao Cai,Yi Gao,Weiping Ding,Yan Zhu

Chemical Science（2024）

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摘要

Here we report a diachronic evolvement from tetra-icosahedral Au30Ag12(CCR)24 to quasi-hcp (hexagonal close-packed) Au47Ag19(CCR)32 which might be proceeded by the interface shrinking followed by the core rearrangement and surface polymerization.

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