Investigation of emission plane control in GaInN/GaN multiple-quantum shells for efficient nanowire-based LEDs

Soma Inaba,Weifang Lu,Ayaka Shima, Shiori Ii, Mizuki Takahashi, Yuki Yamanaka, Yuta Hattori, Kosei Kubota,Kai Huang,Motoaki Iwaya, Tetsuya Takeuchi,Satoshi Kamiyama

NANOSCALE ADVANCES(2024)

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摘要
Significant attention has been directed toward core-shell GaInN/GaN multiple-quantum shell (MQS) nanowires (NWs) in the context of high-efficiency micro light-emitting diodes (micro-LEDs). These independent three-dimensional NWs offer the advantage of reducing the impact of sidewall etching regions. Furthermore, the emitting plane on the sidewalls demonstrates either nonpolar or semipolar orientation, while the dislocation density is exceptionally low. In this study, we assessed how changes in the NW morphology are affected by GaInN/GaN superlattice (SL) structures grown at varying growth temperatures, as well as control of the emission plane via the p-GaN shell and emission sizes. The SL growth rate was enhanced at elevated growth temperatures, accompanied by the shrinkage of the (0001)-plane and expansion of the (1101)-plane on the NWs. The samples exhibited a higher light output when the SLs were grown at elevated temperatures compared to those grown with lower temperatures. A similar trend was observed for the samples with a gradual temperature transition during the growth. These findings indicate that the dimensions of the (0001)-plane can be controlled through SL growth, which in turn influences the emission properties of NW-LEDs. In addition, the emission properties of NW-LEDs with different growth time p-GaN shells and different emission sizes were investigated. Based on the NW-LED characteristics, it was revealed that the weak emission of the (0001)-plane was the dominant factor for the limited light output, and the most effective way to realize high efficiency devices is to suppress current injection into the apex or minimize the grown (0001)-plane region. Overall, it is one promising way to control the emission planes of NWs, which holds significant relevance for the potential application of NW-LEDs in the realm of micro-LEDs. To improve the emission properties of multiple-quantum-shells nanowire-based LEDs, we assessed the effect of GaInN/GaN superlattices grown at varying growth temperatures, as well as the control of emission plane via p-GaN shell and emission sizes.
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