Solvatochromism of a saddle-distorted cationic Zn(II)-porphyrin complex

Hidemi Ochiai,Tomoya Ishizuka, Hiro Tanaka,Yoshihito Shiota,Kazunari Yoshizawa,Takahiko Kojima

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES（2024）

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摘要

A saddle-distorted and cationic Zn(II)-porphyrin complex was revealed to exhibit solvatochromism in organic solvents, depending on the donor numbers. The color change was derived from the alteration of the HOMO-LUMO gap caused by the distortion of the porphyrin mean plane due to solvent coordination.

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关键词

Solvatochromism,Saddle Distortion,Bromination,Donor Number

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