Metallaaromaticity involving a d⁰ early transition metal centre: synthesis, structure, and aromaticity of tantallapyridinazirine complexes

Jingting Yang,Xin Xu,Zhenyang Lin,Zuowei Xie

Chemical Science（2024）

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摘要

Though late transition metal aromatic metallabenzenes and related heteroatom-containing analogues have been well studied, the corresponding aromatic early transition metal complexes remain elusive.

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Metallaaromaticity involving a d0 early transition metal centre: synthesis, structure, and aromaticity of tantallapyridinazirine complexes

Metallaaromaticity involving a d⁰ early transition metal centre: synthesis, structure, and aromaticity of tantallapyridinazirine complexes