The Development of a Stable and Practical Saturated Reference Electrode for Molten Chloride Salt Systems
Journal of the Electrochemical Society(2024)
摘要
A simply constructed, stable, Ni/Ni2+ saturated reference electrode (SRE) has potential to measure thermodynamic behavior of molten chloride salts more reliably. Like the Ag/Ag+ reference electrode (RE), the Ni/Ni2+ SRE is made of commercially available materials. Initial experiments in molten CaCl2 and LiCl show the Ag/Ag+ RE potential drifting two times faster than the SRE. Furthermore, experiments show the replicability of SREs by comparing two Ni/Ni2+ SREs with different compositions of NiCl2 which is supportive of saturated phase behavior.
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关键词
molten salts - high temperature molten salts,reference electrode,electroanalytical electrochemistry,silver/silver chloride reference electrode
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