The Institute of Problems of Chemical Physics (IPCP) (Russian: Институт проблем химической физики РАН) of the Russian Academy of Sciences (RAS) is the largest Institute of the research center in Chernogolovka. The Institute consists of 10 scientific departments and about 100 laboratories each one held by an independent research groups. The staff of the Institute counts nearly 1500 people, among them more than 100 Professors and 350 PhD..
We propose an algorithm to create an arbitrary n-qubit pure quantum superposition state with precision of m-decimals (binary representation) for each probability amplitude. The algorithm uses one-qubit rotations, Hadamard transformations and, C-NOT operations with multi-qubit controls. The depth of the circuit is O(2(n)n), its space is O(n). We emphasize that the parameters of the utilized unitary transformations are predicted in advance by the required precision and therefore there is no classical calculation supplementing this quantum algorithm. Finalizing the state-creation we perform the measurement of the ancilla state with a certain desired output with the purpose of removing all the garbage from the created superposition state. If n and m are independent and n >> m, the probability of access to the desired ancilla-state (success probability) is similar to 2(-n), which requires O(2(n)) runs of the algorithm and leads to the overall depth O(4(n)n). However, the situation can be significantly improved by replacing the usual measurement with the controlled measurement of the ancilla state that, first of all, removes the garbage part of the superposition state and, second (and most important), allows to avoid both the problem of small success probability to the desired ancilla state and multiple runs of the algorithm. As a consequence, the depth of the algorithm is O(2(n)n) in this case. If m serves to provide the required fidelity of state approximation, then the above parameters increase. This algorithm can be a subroutine generating the required input state in various algorithms, in particular, in matrix-manipulation algorithms developed earlier.
Carbon monoxide oxidation catalysts comprising Pt clusters on titanium dioxide with an oxide particle size of 6 and 20 nm have been synthesized. The catalysts have been studied using TEM, XRD, and XPS techniques, and it has been found that platinum clusters coated with a mixture of platinum oxides are formed on the support surface. The coherent scattering region of the Pt cluster is close to 5–6 nm for the studied oxide supports. The catalytic properties in the CO oxidation reaction at 295 K and low CO concentrations (less than 100 mg/m 3 ) have been examined. The catalyst based on titania with a particle size of 20 nm and a platinum loading of 10 wt % has been found to have the CO oxidation rate 100 times higher than that on platinum black with a specific surface area of 30 m 2 /g. The catalysts are promising for use in catalytic air purification systems.
Here, we study the effect of the Dzyaloshinskii-Moriya interaction (DMI) on magnetic nuclei expansion in Pt/Co/Ir/Co/Pt perpendicular synthetic ferrimagnets. Magnetization reversal is explored as a response to the HMI, affecting the expansion of the magnetic nuclei. We report a nontrivial inverted dependence of the velocity of the double domain wall on the in-plane (IP) magnetic field. This effect is due to competition of the DMI contributions, resulting in effective fields of different signs in the two Co layers. We report a macroscopic manifestation of the HMI as magnetization reversal accelerated by the applied IP magnetic field. Accelerated magnetic relaxation is provided by the DMI-induced ellipticity of the magnetic nuclei, the spreading of which is accompanied by an enhanced number of nuclei contacts in comparison with round nuclei in the absence of an IP field. The obtained results clarify how the DMI contributes to macroscopic magnetic relaxation in the presence of the interlayer Heisenberg exchange interaction in synthetic ferrimagnets with perpendicular anisotropy.
The purpose of this article is to answer the question of how symmetry helps us to investigate and understand the properties of nanoscopic magnetic clusters with complex structures. The systems of choice will be the three types of polyoxometalates (POMs): (1) POMs containing localised spins; (2) reduced mixed-valence (MV) POMs; (3) partially delocalised POMs in which localised and delocalised subunits coexist and interact. The theoretical tools based on various kinds of symmetry are the following: (1) irreducible tensor operator (ITO) approach based on the so-called "spin-symmetry" and MAGPACK program; (2) group-theoretical assignment of the exchange multiplets based on spin- and point symmetries; (3) group-theoretical classification of the delocalised electronic and electron-vibrational states of MV POMs; (4) general approach (based on spin symmetry) to evaluate the energy levels of large MV clusters and the corresponding MVPACK program; (5) computational approach (employing point symmetry) to solve multidimensional non-adiabatic vibronic problems in the nanoscopic systems realized as VIBPACK software. We made it our goal to avoid a conventional deductive style of presentation. On the contrary, we first consider specially selected complex POMs and then show by what methods and in what way the theoretical problems arising in the description of the properties of these molecules can be properly solved.
Organic photochromic compounds are attracting great interest as photoswitchable components of various bioconjugates for using in photopharmacology, targeted drug delivery and bio-imaging. Here we report on the synthesis of two novel molecular hybrids of indoline spiropyrans and alpha-lipoic acid via an esterification reaction. Preliminary photochemical studies revealed photochromic activity of 5-methoxy-substituted spirocompounds in their acetonitrile solutions. Both hybrid spiropyrans along with their parent substances in the hybrids were tested for the short-term cytotoxicity on HeLa cell cultures. The results of cytotoxicity studies showed unpredictable biocompatibility of the hybrids in comparison with the parent hydroxyl-substituted spiropyrans and α-lipoic acid, especially at the relatively high concentration of 2 mM. Using flow cytometry, we demonstrated that the both hybrids induced antioxidant response in the model cells. After the 24 h treatment, the hybrids administered at lower (500 µM) concentration caused suppressed cytosolic ROS and/or induced cellular thiols. At higher concentration, one of the hybrids demonstrated properties qualitatively similar to alpha-lipoic acid, yet far more strong. Together, flow cytometry results suggested that both hybrids of spiropyrans possess emergent biochemical and signaling antioxidant properties, exceeding those of alpha-lipoic acid.
