Ultra-high-temperature ceramic (UHTC) coatings offer a promising route to extending cutting tool service life under severe conditions. This work evaluates the tribological behaviour and wear regime transitions of ZrB2–SiC/ZrO2 coatings, deposited by physical vapour deposition (PVD) onto ASSAB-17 high-speed steel tool bits, during dry turning of Ti-6Al-4V. Structural, microstructural, mechanical, and tribological characterisation was performed by X-ray diffraction (XRD), scanning electron microscopy (SEM), nanoindentation, and pin-on-disc testing under three pressure–velocity (PV) severity levels, with worn surfaces analysed by SEM and profilometry. The coating exhibited a nanostructured ZrB2/β-SiC/t-ZrO2 architecture with a hardness (H) of 24 ± 3 GPa, a hardness-to-reduced-elastic-modulus ratio (H/Er) of 0.100, and an elastic resistance to plastic deformation (H3/Er2) of 0.240 GPa. Three tribological regimes were identified: running-in, steady-state sliding, and progressive degradation, with the highest severity (PV = 6.0 N·m/s) triggering degradation beyond approximately 620 m, a more than one-order-of-magnitude rise in wear rate, and the only case exceeding the tool-life criterion of maximum flank wear (VBmax = 0.30 mm) according to ISO 3685. The main advantage of the proposed approach is that it condenses tool-life-relevant behaviour into a single, easily measurable severity parameter, the PV product, directly applicable to coating design and the selection of safe machining-condition windows. The overall behaviour is consistent with a mechanism governed by the stability and regeneration capacity of a protective tribofilm. As the composition of this layer was not directly characterised, this mechanism is proposed as a phenomenological interpretation, from which a PV threshold is derived as a design criterion for UHTC coatings.
Enclosed reinforced concrete structures subjected to internal blast loading represent a critical safety concern in infrastructure applications where detonations may occur within confined spaces. Although circular cross-sections have been widely adopted for blast-resistant containment structures, systematic quantitative comparisons of internal blast responses between circular and square enclosed configurations under progressive charge weight conditions remain limited. LS-DYNA finite element simulations are conducted under four trinitrotoluene (TNT) charge weight conditions ranging from 1200 to 2500 kg, and the failure-inducing blast load is defined as the minimum charge weight at which continuous concrete element deletion first occurs in the roof or side-wall region. In this study, the failure-inducing blast load is interpreted as an erosion-based comparative indicator under the adopted empirical blast-loading framework rather than as an absolute real-world confined-blast failure threshold. The roof failure-inducing blast load is identical for both structures at 1200 kg, whereas the side-wall failure-inducing blast loads are 2500 kg for the circular structure and 1500 kg for the square structure, indicating approximately 67% higher side-wall blast resistance in the circular structure. This difference is attributed to the membrane action of the curved wall, which redistributes internal blast-induced lateral pressure along the circumferential direction and limits out-of-plane deformation. Under the 2500-kg condition, the peak side-wall displacement of the square structure is 161.6% higher than that of the circular structure, whereas its peak roof displacement is 33.3% lower. Axial strains at all reinforcement locations remain within the elastic range, confirming that concrete damage is governed by the low tensile capacity of concrete rather than reinforcement yielding.
In this work, the structural, optical, vibrational, and stability properties of a series of AlxAsx nanostructures are systematically investigated using density functional theory (DFT) and time-dependent density functional theory (TD-DFT). Starting from the fundamental cubic-like Al4As4 building block, progressively larger nanostructures were constructed through directional elongation and structural rearrangements, allowing for the exploration of one-dimensional chains, two-dimensional planar structures, and several exotic geometries. The calculated UV–visible absorption spectra reveal that structural dimensionality and topology strongly influence the electronic transitions of the nanostructures, with elongated and distorted configurations exhibiting broader absorption features and richer spectral distribution. Vibrational analysis shows that increasing structural complexity and reducing symmetry lead to a higher density of IR-active modes and more complex infrared spectra. The stability of the nanostructures is evaluated through binding energy calculations, which indicate a clear size-dependent stabilization trend, with the Al24As24-L1 configuration exhibiting the highest stability among the examined systems. In addition, the calculated HOMO-LUMO gaps reveal the semiconducting character of the clusters and demonstrate their sensitivity to geometric topology. The present results establish clear structure–property relationships between dimensional growth and the optical response of AlAs nanoparticles and provide theoretical reference data for future experimental investigations of III-V semiconductor nanostructures.
The persistent accumulation of antibiotic pollutants in aquatic environments poses potential threats to ecological safety and human health, highlighting the importance of developing low-cost, high-performance adsorbents for their efficient removal. In this study, a hydrothermal method was employed to prepare highly dispersed coal gangue-based calcium silicate hydrate (CSH) adsorbents. The structural characteristics, adsorption performance, and adsorption mechanisms of the material were systematically investigated. The as-prepared CSH exhibited an interwoven nanorod/nanosheet composite morphology with a more developed pore structure and a higher specific surface area. Kinetic analysis indicated that the adsorption process followed a pseudo-second-order model and involved both Boyd diffusion and intraparticle diffusion, with liquid-film diffusion likely serving as the primary rate-limiting step. Isotherm analysis revealed that the adsorption behavior was well described by the Langmuir model, suggesting monolayer adsorption, with a theoretical adsorption capacity (Qm) of 129.29 mg/g. Thermodynamic analysis further demonstrated that the adsorption of CIP onto CSH was a spontaneous and endothermic process. Combined characterization results and theoretical calculations suggested that the adsorption of CIP by CSH was mainly governed by surface oxygen containing active sites, accompanied by electrostatic interactions, hydrogen bonding, and possible surface coordination effects. In addition, CSH maintained excellent adsorption performance and structural stability in the presence of coexisting ions, in tap water systems, and after repeated adsorption–desorption cycles. This study not only enables the high-value utilization of coal gangue but also provides new insights into the development of low-cost adsorbent materials for antibiotic removal.
Polymer-derived ceramics (PDCs) technology has been established for over five decades as a versatile route for the fabrication of advanced bioceramic materials. However, conventional processing routes for bioceramics, such as melt-quenching and sol–gel methods, still present significant limitations, including high processing temperatures, limited compositional flexibility, long processing times, and difficulties in fabricating complex and highly porous structures required for biomedical applications. In this context, increasing attention has been devoted to polymer-derived ceramics as an alternative approach for the fabrication of bioceramic materials. In this approach, preceramic polymers are converted into ceramic phases through thermal treatment in air or inert atmosphere (e.g., nitrogen), enabling low-temperature processing, high compositional flexibility, and precise control over phase evolution and microstructure. These features make the polymer-derived Ceramic route particularly attractive for the fabrication of complex and functional bioceramic architectures. This review provides an overview of the polymeric precursors employed for the synthesis of Polymer Derived Ceramic-based bioceramics, with particular emphasis on inorganic polymers, typically characterized by a siloxanic backbone, and the mechanisms governing their ceramization behavior. Special attention is given to emerging trends, including the integration of polymer-derived ceramics with additive manufacturing techniques and the development of functional systems for biomedical applications.
The determination of the linear optical constants of solids is an important part of solid state optical characterization. Reflection spectroscopy and ellipsometry of surfaces or thin solid films represent established techniques to access those optical constants; however, they may suffer from ambiguity in the obtained optical constants. We discuss methods for identifying the physically meaningful solution from the solution multiplicity, making use of a proper combination of independent measurements. Elaborating contours of constant reflectance (iso-reflectance curves) facilitates the reliable identification of correct optical constants. A numerical criterion is further provided to select suitable combinations of measurements. The procedure is demonstrated through its application to simulated spectra of a Nb2O5 film in the spectral region where the onset of the fundamental absorption edge is observed.
This work presents a comprehensive investigation of the thermal decomposition of nickel oxalate dihydrate as a precursor for the synthesis of porous NiO, with particular emphasis on microstructural formation and evolution. The transformations occurring at successive stages of the reaction were examined using SEM, TEM, N2 adsorption, TG–DSC–MS, and in situ powder XRD, enabling the mechanisms of pore formation to be elucidated. The decomposition results in the formation of a porous pseudomorph composed of NiO nanoparticles with an average size of approximately 4 nm. This is the first time that the resulting microstructure has been shown to exhibit hierarchical, bimodal porous architecture. During dehydration, macropores are generated as a result of crystal fragmentation into blocks several hundred nanometers in size. Subsequent oxalate decomposition leads to the formation of mesoporous aggregates composed of nanometer-sized particles. The factors governing the parameters of the porous microstructure are analyzed. The resulting NiO, with its hierarchical pore structure, shows significant potential for applications in heterogeneous catalysis, gas sensing, and as electrodes for supercapacitors, lithium-ion batteries, and photoelectrochemical devices, as its macropores facilitate mass transport by reducing diffusion resistance while its mesopores provide a large accessible surface area for adsorption and catalytic reactions.
An experimental investigation of the Cu-As-Sb ternary system in the Cu-rich region led to the identification of a new intermetallic phase, Cu5(As,Sb)2. The compound crystallizes in the orthorhombic Mg5Ga2-type structure (oI28, Ibam), analogous to the binary parent phase Cu5As2, with lattice parameters a = 5.968–5.977(1) Å, b = 11.550–11.565(3) Å, c = 5.530–5.573(3) Å. Similar to the parent Cu5As2 phase, the ternary compound forms with slight Cu under stoichiometry and exhibits a limited compositional range, with no continuous solid solubility between the binary and ternary phases. The phase formation, compositional stability, and decomposition behavior were systematically studied using a combination of powder and single-crystal X-ray diffraction (XRD, including Rietveld refinement), metallographic analysis with optical and scanning electron microscopy with energy-dispersive X-ray spectroscopy (LOM, SEM-EDXS), electron backscatter diffraction (EBSD) and thermal analysis (DTA, DSC). The results reveal that Cu5(As,Sb)2 is a high-temperature phase forming peritectically at 650–635 °C and stable only within a limited temperature interval. No continuous solid solubility exists between the ternary compound and the parent binary phase Cu5As2. Its formation occurs in strong competition with that of two other close neighboring solid-solution compounds, [Cu3−x(As1−ySby) (Cu3P-type; hP24, P63cm) and Cu3−x(As,Sb) (Cu9TeSb2-type; cP32, Pm−3n)], reflecting a complex interplay between composition, solubility ranges and thermal history. No evidence for the existence of high-temperature (HT) and low-temperature (LT) polymorphic phases was found for either the binary compound Cu5As2 or the ternary compound Cu5(As,Sb)2. Electrical resistivity measurements on a quenched sample indicate metallic behavior. These findings provide new insight into phase stability and structure–property relationships in Cu-As-Sb alloys and contribute to the understanding of competing intermetallic phases in this system.
Two-dimensional molybdenum disulfide (MoS2) has emerged as a promising candidate for next-generation electronics and optoelectronics; however, its scalable synthesis with precise control over domain size and film continuity remains challenging. Herein, we report a physical vapor deposition (PVD)-assisted chemical vapor deposition (CVD) strategy for the controllable growth of high-quality monolayer MoS2. By thermally evaporating an ultrathin (3 nm) MoO3 precursor film, spontaneous post-deposition dewetting yields a porous honeycomb morphology that significantly enhances vapor–solid reaction kinetics during subsequent sulfurization. Crucially, by modulating the argon carrier gas flow rate to regulate the local sulfur chemical potential, we achieve distinct growth regimes: a high flow rate (70 sccm) suppresses nucleation density, enabling isolated triangular and hexagonal single crystals with lateral dimensions up to 500 μm, whereas a reduced flow rate (50 sccm) promotes high-density nucleation and coalescence into continuous centimeter-scale polycrystalline films. Comprehensive structural and optical characterizations, including atomic force microscopy, Raman spectroscopy, photoluminescence, and X-ray photoelectron spectroscopy, confirm that the synthesized MoS2 exhibits prototypical monolayer thickness (~0.7 nm), well-defined local crystallinity and a direct bandgap emission at 1.84 eV. This work establishes a robust, scalable, and highly tunable route for synthesizing large-area 2D TMDs tailored for advanced device integration.
Piezoelectric semiconductor combines the unique properties of semiconducting characteristics and piezoelectric effect together, providing a universal methodology to modulate piezoelectric semiconductor device’s performance by simply introducing mechanical strain. To reveal the device physics beneath the piezoelectric modulation, in this work, a multiphysics COMSOL 6.0 simulation was employed to investigate the modulation of Si/GaN heterojunction PN diode characteristics via piezoelectric-induced interface polarization charges. The effects of charge polarity and density on forward recovery, reverse recovery, and irradiation responses were systematically analyzed. The results demonstrate that negative interface charges enhance carrier injection and accelerate device activation, whereas positive charges suppress overshoot and stabilize transient voltage behavior. During reverse recovery, negative charges shorten the storage delay and reduce the reverse peak current, improving the switching speed, whereas positive charges cause slower recovery. Under irradiation, the interface polarization charges modulate the photocurrent density by altering the depletion width and carrier collection efficiency; negative charges notably enhance the photocurrent in partially depleted devices. Furthermore, the influence of the polarization charges diminishes with increasing device length or doping concentration, as the built-in charge and electric field effects dominate. This study elucidates the physical mechanisms of piezoelectric charge control in Si/GaN heterojunctions and provides theoretical guidance for the design of high-speed, low-loss, and radiation-tunable power and optoelectronic devices.
KTaO3 (KTO) is a quantum paraelectric perovskite oxide which belongs to the cubic space group Pm3¯m in a large temperature range. Polar optical modes with a T1u symmetry of KTO are infrared-active and Raman-inactive according to the centrosymmetric exclusion principle of the selection rule. In general, the soft modes responsible for ferroelectric instability are infrared-active and Raman-inactive in the paraelectric phase. Therefore, there are still not enough studies on Raman-inactive soft modes and related phonon polaritons. In the present study, Raman-inactive polar modes and related polaritons of KTO crystals are studied by Terahertz Time-Domain spectroscopy (THz-TDS) and FTIR. The real and imaginary parts of a dielectric constant along the [100] axis are uniquely determined by transmission and reflection THz-TDS without any fitting in the low-frequency range between 6 and 225 cm−1, which covers the two lowest-frequency polar modes. The reflectivity is determined by reflection FTIR in the range between 50 and 1200 cm−1, and the complex dielectric constant is also estimated by the fitting in the range between 6 and 1200 cm−1. The phonon–polariton dispersion relations of the real and imaginary parts of the polariton wavevector are also studied in the range between 6 and 1200 cm−1. The crossover from photon-like to phonon-like polaritons and related polariton decay are observed, while no anomaly related to polariton scattering and coupling to other elementary excitations is observed in the polariton dispersion.
The present study addresses the fabrication of porous gyroid architectures by additive manufacturing from preceramic polymer feedstocks. Photocurable emulsions were engineered by combining a silicone powder with acrylate monomers and dispersing an emulsified secondary phase of calcium nitrate. The formulations showed light-curing behaviour compatible with digital light processing vat photopolymerization (DLP-VPP), enabling high-fidelity replication of triply periodic minimal surface (TPMS) gyroids (designed porosity: 85 vol.%). After pyrolysis in nitrogen at 700 °C, the lattices converted into CaO–SiO2-derived amorphous matrices embedding an in situ turbostratic/pyrolytic carbon fraction, as suggested by the photothermal response and preliminary impedance behaviour, although the latter was measured in liquid electrolyte and therefore does not isolate electronic transport. To improve robustness during polymer-to-ceramic conversion, pharmaceutical borosilicate waste glass (BASG) was added as a passive filler (30–70 wt.%). The waste-glass phase acts as a passive filler that improves processing robustness and can mitigate shrinkage-induced damage during pyrolysis, while remaining electrically insulating (dielectric) and therefore not directly contributing to electronic conduction. The resulting structures combine high surface-to-volume ratio, controlled open porosity, and structural integrity with electrochemical responsiveness under the adopted test conditions, making them promising architected platforms for electrochemical components where interconnected porosity is advantageous.
Using the molecular dynamics method, the compression of nickel nanoparticles with a nanocrystalline structure was simulated. The influence of the nanoparticle size (from 2 to 20 nm) and the average grain size within it (from 2 to 8 nm) on the compressive strength and on the strain at which the maximum stress is reached was investigated. In addition, the stability of the nanocrystalline structure of the nanoparticles was studied as a function of temperature and grain size. It is shown that the smaller the diameter of the nanocrystalline particle, the higher the compressive strength and the strain at which the maximum stress is reached. A decrease in grain size leads to a reduction in compressive strength, which is associated with the main mechanism of plastic deformation of nanocrystalline nanoparticles, namely, grain boundary sliding. At the first stage of deformation, the entire particle structure typically rotates until the maximum value of the stress vector projection onto the preferred slip plane is reached, which, in the case of a nanocrystalline structure, is determined by the mutual orientation of the grain boundaries. Grain boundaries elongated approximately along a single plane represent, in this case, the preferred slip plane.
Enhancing the solubility and processability of graphene remains a critical challenge, limiting its integration into advanced materials systems. In this work, poly(tert-butyl acrylate) (PtBA) and poly(N-isopropyl acrylamide) (PNIPAM) were grafted onto graphene via controlled atom transfer radical polymerization (ATRP) to create well-defined polymer-graphene hybrids with tunable interfacial properties. ATRP enabled the synthesis of PtBA and PNIPAM homopolymers with narrow molecular weight distributions and systematically varied chain lengths (4-18 kDa), allowing direct correlation between polymer architecture and material performance. Notably, the thermos-responsive behavior of PNIPAM was strongly dependent on chain length, highlighting the importance of controlled polymer design. Raman and FTIR spectroscopy confirmed successful grafting and chemical modification of the graphene surface. In addition, pilot studies demonstrate the ATRP synthesis of PtBA-b-PNIPAM block copolymers and their hydrolysis to PAA-b-PNIPAM, providing a platform for future development of multifunctional graphene interfaces. Overall, this study establishes a versatile and precisely controlled route for engineering polymer-grafted graphene with enhanced solubility and tunable functionality, enabling broader applications in smart materials and hybrid nanocomposites.
Cr2O3-based ceramic coatings are widely used in wear-critical applications; however, their tribological performance under dry sliding conditions can be limited by brittleness and frictional instability. In heavy-duty vehicles, the king pin–bushing contact operates under severe dry sliding conditions, motivating the investigation of composite Cr2O3–nTiO2 coatings as a potential surface engineering solution. In this study, Cr2O3–TiO2 coatings containing 0, 10, 20, 30, and 40 wt% TiO2 were deposited by atmospheric plasma spraying (APS) from mechanically mixed powders. Phase composition was analyzed by X-ray diffraction using an X’Pert PRO MRD diffractometer, while microstructure and elemental distribution were examined by scanning electron microscopy (SEM) coupled with energy-dispersive X-ray spectroscopy (EDS) on a FEG Quattro C microscope. Mechanical properties were evaluated by Vickers microhardness, instrumented indentation and scratch testing, while dry sliding wear behavior was assessed by pin-on-disc tests performed on a CETR UMT-2 tribometer against a bronze counterbody, with continuous monitoring of the coefficient of friction (COF). The results show that plasma spraying produces lamellar composite coatings with intrinsic porosity and locally modified phase composition. Cr2O3-rich coatings exhibit higher hardness (1198 HV2 compared with 877 HV2 for Cr2O3–40TiO2 corresponding to an increase of approximately 36%) and improved resistance to indentation, reflected by lower penetration depths and higher elastic modulus values (134 GPa for S0 compared with 77 GPa for S2). These coatings also exhibit a more stable friction response and reduced material transfer from the bronze counterbody, as confirmed by the lower mass loss of the pins (0.0295 g for S0 compared with 0.0473 g for S4, corresponding to a reduction of about 38%). Increasing TiO2 content leads to changes in friction stability and wear behavior associated with microstructural heterogeneity. These findings indicate that the sliding wear performance of Cr2O3–nTiO2 coatings is governed by elastic–plastic stability under localized contact loading and support their applicability for dry sliding king pin–bushing systems in heavy-duty vehicles.
The recycling of carbon fiber-reinforced polymers (CFRPs), particularly carbon fiber-reinforced epoxy polymers (CFREPs), is a challenging problem because of their broad application spectrum, the amount of laminates produced per year, and the cost per kg of the carbon fiber fabric. Recently, several papers were published on the recycling of CFREPs through solvothermal methods that allow the recovery of the carbon fiber fabrics with a relatively low environmental impact. In the present paper, for the first time, the effect of the presence of flame retardants is discussed. A carbon fiber-reinforced epoxy polymer (CFREP) charged with P-, Zn-, B- and Al-based flame retardants, supplied by the aerospace industry, was subjected to a double-step solvothermal treatment. The epoxy matrix was successfully dissolved in monoethanolammine after a preswelling step in acetic acid. The experimental results show that the proposed process allows the full recovery of the carbon fabric with its original sizing layer without injury to the fiber. As confirmation, CFREP laminates produced with the recycled carbon fiber fabrics exhibited mechanical properties close to that of laminates obtained from the virgin epoxy/carbon prepreg. Contrary to what is reported in the literature, the present paper also shows that, in the studied case, whilst acetic acid treatment promotes swelling, it also causes the formation of a degraded surface layer that would impede complete removal of the polymeric matrix and full recovery of the carbon fabric if only acetic acid was used. On the basis of the known mechanism of flame retardancy of phosphates and borates, the degraded layer formation is attributed to the acidic character of the acetic acid. It is worth pointing out that the paper suggests, therefore, that the presence of flame retardants may strongly affect the solvothermal processes.
Poly(vinyl alcohol) (PVA)/montmorillonite (MMT)/Ti3C2Tx (MXene) nanocomposite membranes (PVA/MMT/MXene) were developed and evaluated in terms of their mechanical properties, mesoporosity, and adsorption performance toward Pb2+ ions and methylene blue (MB). The incorporation of MMT and MXene resulted in a strong synergistic reinforcement, increasing the ultimate tensile strength from 10 to 20 MPa, the Young's modulus from 14.7 to 29.5 MPa, and reducing the swelling ratio from 2.0 to 1.1 g & centerdot;g(-1). BJH porosimetry revealed a refined and interconnected mesoporous structure, with the cumulative pore volume increasing from 0.134 to 0.448 cm(3)& centerdot;g(-1). In adsorption experiments (mono-solute systems, 25 degrees C), the ternary membrane achieved high uptake capacities of 55 mg & centerdot;g(-1) for Pb2+ and 80 mg & centerdot;g(-1) for MB, outperforming binary PVA/MMT and neat PVA. Statistical-physics modeling provided microscopic descriptors consistent with the experimental isotherms: Pb2+ adsorption follows a monolayer regime (n approximate to 1), whereas MB exhibits multilayer behavior (n > 1) with a higher site density (Nm approximate to 1.6 mmol & centerdot;g(-1)). These results demonstrate that the hybrid 2D-2D architecture of MMT and MXene significantly enhances the structural robustness, pore accessibility, and adsorption efficiency of PVA-based membranes, highlighting their potential for efficient removal of metal ions and dyes from aqueous media.
Aluminum foam is expected to be applied in various industrial fields as a lightweight, multifunctional material. When it is used as an industrial product, it is essential to form it into the required shape. There have been some attempts to form aluminum foam. However, the formability remains low. In this study, we attempted to form aluminum foam, which was fabricated by heat foaming a precursor, into a flat plate by reheating it above its foaming temperature and then roller forming it. It was found that heating above the foaming temperature and subsequent roller forming enabled the aluminum foam to be formed into a flat plate without causing defects. In a sample in which the precursor was roller-formed immediately after foaming, it was found that compared to the as-foamed aluminum foam, the decrease in porosity was limited to approximately 5%, enabling roller forming while minimizing the influences on pore structures. In samples that were roller-formed after reheating, porosities slightly decreased, but most pores were retained. Even when the aluminum foam was roller-formed to the same thickness as the initial precursor before foaming, the porosities exhibited around 65%, limiting the reduction in porosities to approximately 15% compared to the as-foamed aluminum foam.
Metal-chalcogenide compounds with perovskite-type compositions have drawn increasing attention for their optical properties for solar energy conversion. Herein, a new α-type polymorph of the ternary sulfide SrHfS3 is described, crystallizing in the NH4CdCl3 structure type. The yellow-colored plate-shaped crystals were synthesized at 1173 K using an elemental tin flux in an evacuated sealed tube. Its crystal structure was characterized at room temperature using single crystal X-ray diffraction to form in the orthorhombic Pnma space group, with the refined cell parameters of a = 8.5041(4) Å, b = 3.8004(2) Å, c = 13.8935(6) Å, and V = 449.02(4) Å3. The structure comprises five independent crystallographic sites, having one Sr, one Hf, and three S sites. The structure can be described as containing one-dimensional chains of distorted HfS6 octahedra extending down the b-axis to form 1∞[HfS3]2− strips of edge-sharing octahedra. The Sr atoms act as charge-balancing space fillers in the structure. High-purity bulk samples of α-SrHfS3 could be prepared for measurement of its bandgap by optical diffuse-reflectance spectroscopy, showing a direct bandgap of 2.1(1) eV. Results of electronic structure calculations are consistent with this bandgap and type. The conduction and valence band edges stem from the respective empty Hf d-orbitals and the filled S p-orbital states. In summary, crystal growth of the α-type polymorph of SrHfS3 has been demonstrated using a Sn flux approach, which can facilitate future broader synthetic explorations at lower temperatures.
A ceramic-packaged, dual-layer-stacked System-in-Package (SiP) architecture combines the hermeticity of ceramic substrates with the superior radio frequency (RF) performance of organic substrates to meet the demands for high-density integration, cost-effectiveness, and high performance. This study investigates the issues of thermal mismatch, solder joint contamination, and void formation during the large-area eutectic bonding of the lower organic substrate using Pb70In30 solder through simulation and an experimental approach. The results indicate that: (a) the post-bonding warpage of the organic substrate can be reduced to under 80 µm by optimizing its copper layer thickness, dielectric layer thickness, and cavity/slot distribution, and (b) flux pretreatment can be employed to reduce the Pb70In30 solder in an N2/H2 mixture at a eutectic temperature of 285 °C and a pressure of 1.5 kPa effectively promotes solder spreading, prevents solder joint contamination, and yields a void formation percentage below 10%, a shear strength of 23.66 MPa, and solder overflow exceeding 90%, thereby satisfying the requirements for reliable large-area eutectic bonding. These findings offer guidance for the packaging process design of ceramic-packaged, dual-layer-stacked SiPs.
