Methoden Zur Darstellung Kationischer Rhenium-pentacarbonyl(thiazylhalogenid)-Komplexe / Methods for the Preparation of Cationic Rhenium-pentacarbonyl(thiazylhalide) Complexes | AMiner
Methoden Zur Darstellung Kationischer Rhenium-pentacarbonyl(thiazylhalogenid)-Komplexe / Methods for the Preparation of Cationic Rhenium-pentacarbonyl(thiazylhalide) Complexes
The preparation of [Re(CO)5NSX]+AsF6 - (2a X = Cl, 2b X = Br) is possible (a) by metathesis from [Re(CO)5NSF]+AsF6 - with SiX4, (b) by insertion of the NS+-cation into the metal-halogenbond of Re(CO)5X and (c) by nucleophilic halide addition to the sulfur in the dicationic thionitrosyl complex [Re(CO)5NS]+ +.
原文链接
分享
引用
