Multidimensional Spectroscopy and Imaging of Defects in Synthetic Diamond: Excitation-Emission-lifetime Luminescence Measurements with Multiexponential Fitting and Phasor Analysis

We report the application of phasor analysis and nonlinear iterative fitting to complex spatial and spectroscopic luminescence decay data obtained from multidimensional microscopy of a CVD diamond grown on a HPHT substrate. This spectral and lifetime-resolved analysis enabled spatial mapping of variations in concentrations of nitrogen vacancy (NV) defects in both charge states and the quenching of NV- defects, as well as the identification of SiV- luminescence. These imaging and spectroscopic modalities may be important for reliable fabrication of quantum devices based on such defects in diamond, which will require well-defined and characterised quantum electronic properties.