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    一种丝素蛋白冻干膜的制备方法

    KR200903291B
    发明人
    张锋, 屠洁, 陈明, 黄政杰
    受让人
    UNIV SOOCHOW (USWZ-C), CHANGZHOU SIBODUN BIOTECHNOLOGY CO LTD (CHAN-Non-standard)
    申请人
    WALDA FRANZ, LEDERER FRANZ
    申请号
    A0014191
    申请日
    2006-03-19
    公开(公告)号
    KR200903291B
    公开(公告)日
    1999-07-29
    IPC分类号
    B29C000/00C08J009/12C08L101:00C08J009/00B29C044/34
    CPC分类号
    -
    优先权号
    000004
    优先权日
    1993-07-15
    摘要

    NOVELTY - The center cap (100) has netting thread frame (130) that is provided with the assembler of the powder lead (110). The netting thread (120) is organized as the high elasticity thread. The powder discharge hole (131) of the dish-shaped is provided in which annular recesses (132,133) are inserted. The netting thread frame is provided with the fixing projection (117). The fixing projection is made of the sharp fin type so that the hooking action about the netting thread is facilitated.

    USE - Center cap for cosmetic powder container.

    ADVANTAGE - The productivity of the center cap can be improved and the fabrication cost of the center cap can be lowered, since the failure rate of the center cap and the number of assembly processes can be reduced reliably.

    DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for center cap manufacturing method of cosmetic powder container.

    DESCRIPTION OF DRAWING(S) - The drawing shows the exploded perspective view of the center cap for cosmetic powder container.

    Center cap (100)

    Powder lead (110)

    Fixing projection (117)

    Netting thread (120)

    Netting thread frame (130)

    Powder discharge hole (131)

    Annular recesses (132,133)

    权利要求
    1. A wastewater treatment apparatus comprising: a recirculation chamber; a dosing chamber having no direct fluid connection to the recirculation chamber, and separated therefrom by a substantially vertical chamber wall; a filter layer containing a filter media and being located atop the recirculation and dosing chambers and the substantially vertical chamber wall, the recirculation chamber, the dosing chamber, and the filter layer being located in a single tank; an influent pipe that directs wastewater entering the wastewater treatment apparatus into the recirculation chamber; a recirculation pump located in the recirculation chamber, the recirculation pump pumping the wastewater from the recirculation chamber onto the filter layer; a porous filter underdrain, the wastewater treatment apparatus being configured such that the wastewater flowing through the filter media of the filter layer is directed through the underdrain and is then directed simultaneously into the recirculation chamber and the dosing chamber by gravity; a septic tank return pipe connected to the dosing chamber, a portion of the wastewater being discharged from the wastewater treatment apparatus through the septic tank return pipe back to a septic tank for additional treatment; and an effluent discharge pipe connected to the dosing chamber, the wastewater being discharged from the wastewater treatment apparatus through the effluent discharge pipe for final disposal.
    2. The wastewater treatment apparatus of claim 1 , wherein the chamber wall divides the recirculation chamber and the dosing chamber so that wastewater passing through the underdrain proportionally enters the recirculation chamber and dosing chamber as determined by the placement of the chamber wall.
    3. The wastewater treatment apparatus of claim 1 , further comprising a filter distribution pipe and a spray nozzle for the filter layer, the recirculation pump pumping the wastewater onto the filter media of the filter layer through the filter distribution pipe and the spray nozzle.
    4. The wastewater treatment apparatus of claim 3 , further comprising a screen surrounding the recirculation pump, the screen being configured to prevent the recirculation pump from ingesting debris or solids which would cause the spray nozzle to plug.
    5. The wastewater treatment apparatus of claim 3 , further comprising a filter section vent having an outside vent opening open to the atmosphere, and an opening at the filter layer creating an air space above the filter media of the filter layer, wherein the wastewater pumped through the filter distribution piping and spray nozzle assembly of the filter layer is sprayed into the air space of the filter layer.
    6. The wastewater treatment apparatus of claim 3 , further comprising a filter section riser, a filter section hatch and a filter section hatch handle located over the filter layer to allow access to the filter distribution pipe, the spray nozzle, a spray nozzle support pipe, and the filter media for maintenance and replacement.
    7. The wastewater treatment apparatus of claim 1 , further comprising a dosing pump located in the dosing chamber, the dosing pump pumping the wastewater from the dosing chamber through the effluent discharge pipe.
    8. The wastewater treatment apparatus of claim 7 , further comprising a dosing basin level control, the dosing basin level control activating the dosing pump when the level of wastewater in the dosing chamber reaches a predetermined dosing pump activation level.
    9. The wastewater treatment apparatus of claim 8 , further comprising a dosing pump timer, the dosing pump timer periodically activating the dosing pump, the dosing basin level control disabling activation of the dosing pump when the level of wastewater in the dosing chamber is below a predetermined dosing chamber minimum level, and enabling activation of the dosing pump when the level of wastewater in the dosing chamber is above a predetermined operating level.
    10. The wastewater treatment apparatus of claim 7 , further comprising a control system having an alarm, the control system monitoring an amperage draw by the recirculation pump and the dosing pump, the control system being preset with an acceptable range for the amperage draw, the control system triggering the alarm when the amperage draw goes outside of the acceptable range for the amperage draw.
    11. The wastewater treatment apparatus of claim 1 , further comprising an effluent filter on the effluent discharge pipe, the effluent filter preventing solids from being discharged from the treatment apparatus, the effluent filter including a valve to allow the discharge flow through the filter to flush solids and debris from the filter through a filter flush outlet pipe back to the recirculation chamber.
    12. The wastewater treatment apparatus of claim 1 , further comprising a treated effluent discharge control system having first and second electric valves on the effluent discharge pipe and the septic tank return pipe, respectively, the first and second electric valves being controlled by the control system selectively to discharge treated effluent to the effluent disposal system and return the treated effluent back to the septic tank to dilute incoming wastewater and for further treatment, the control system opening and closing the first and second valves based on predetermined depths of wastewater in the dosing chamber as measured by the dosing basin level control.
    13. The wastewater treatment apparatus of claim 1 , further comprising a treated effluent flow sensor on the effluent discharge pipe, the flow sensor measuring the velocity of the effluent in the effluent discharge pipe, and a control system converting the velocity into a daily flow amount and storing the flow information.
    14. The wastewater treatment apparatus of claim 1 , further comprising a recirculation pump timer, the recirculation pump timer periodically activating the recirculation pump.
    15. The wastewater treatment apparatus of claim 1 , further comprising a recirculation basin level control, the recirculation basin level control activating the recirculation pump when the level of wastewater in the recirculation chamber reaches a predetermined recirculation chamber maximum level.
    16. The wastewater treatment apparatus of claim 1 , wherein the recirculation chamber includes a recirculation basin and a recirculation pump chamber, the recirculation basin and the recirculation pump chamber being connected by a recirculation conduit.
    17. The wastewater treatment apparatus of claim 1 , wherein the dosing chamber includes a dosing basin and a dosing pump chamber, the dosing basin and the dosing pump chamber being connected by a dosing conduit.
    18. The wastewater treatment apparatus of claim 1 , further comprising a control system having an alarm, the control system monitoring ponding of water on the filter media of the filter layer, the control system triggering the alarm when ponding of water is detected on the filter media of the filter layer.
    19. The wastewater treatment apparatus of claim 1 , further comprising a control system including a modem card, the modem card being activated by at least one of a recirculation chamber level alarm and a dosing chamber level alarm, the modem card, when activated, initiating a call to a preset phone number to notify a responsible person of at least one of the recirculation chamber level alarm and the dosing chamber level alarm.
    20. The wastewater treatment apparatus of claim 1 , further comprising a tablet chlorinator installed in the dosing chamber, the tablet chlorinator providing chemical chlorine to the treated effluent for disinfection.
    21. A wastewater treatment apparatus comprising: a recirculation chamber; a dosing chamber having no direct fluid connection to the recirculation chamber, and separated therefrom by a substantially vertical chamber wall; a filter layer containing a filter media and being located atop the recirculation and dosing chambers and the substantially vertical chamber wall, the dosing chamber, and the filter layer being located in a single tank; an influent pipe that directs wastewater entering the wastewater treatment apparatus into the recirculation chamber; a recirculation pump located in the recirculation chamber, the recirculation pump pumping the wastewater from the recirculation chamber onto the filter layer, the wastewater treatment apparatus being configured such that the wastewater flowing through the filter media of the filter layer thereafter simultaneously flows into the recirculation and dosing chambers by gravity; a septic tank return pipe connected to the dosing chamber, a portion of the wastewater being discharged from the wastewater treatment apparatus though the septic tank return pipe back to a septic tank for additional treatment; and an effluent discharge pipe connected to the dosing chamber, the wastewater being discharged from the wastewater treatment apparatus through the effluent discharge pipe for final disposal.
    22. The wastewater treatment apparatus of claim 21 , further comprising a porous underdrain for the filter layer, the wastewater flowing through the filter media of the filter layer being directed through the underdrain and into the recirculation chamber or the dosing chamber.
    23. The wastewater treatment apparatus of claim 22 , wherein the chamber wall divides the recirculation chamber and the dosing chamber so that wastewater passing through the underdrain proportionally enters the recirculation chamber and dosing chamber as determined by the placement of the chamber wall.
    24. The wastewater treatment apparatus of claim 21 , further comprising a filter distribution pipe and a spray nozzle for the filter layer, the recirculation pump pumping the wastewater onto the filter media of the filter layer through the filter distribution pipe and the spray nozzle.
    25. The wastewater treatment apparatus of claim 21 , further comprising a treated effluent discharge control system having first and second electric valves on the effluent discharge pipe and the septic tank return pipe, respectively, the first and second electric valves being controlled by the control system selectively to discharge treated effluent to the effluent discharge pipe and the septic tank return pipe.
    说明书
    [0001]CROSS-REFERENCE TO RELATED APPLICATIONS
    [0002]This application is based on and claims priority of Japanese Patent Application No. 2004-022581 filed on Jan. 30, 2004, the entire contents of which are incorporated herein by reference.
    [0003]BACKGROUND OF THE INVENTION
    [0004](a) Field of the Invention
    [0005]The present invention relates to a semiconductor device and a method of manufacturing the same. More specifically, the present invention relates to a semiconductor device having a package structure in which a semiconductor element (chip) is mounted inside a wiring board for a reduction in thickness, and relates to a method of manufacturing the same.
    [0006](b) Description of the Related Art
    [0007]Heretofore, semiconductor devices having various forms have been proposed in which a chip is mounted inside a wiring board. As an example thereof, there is a package structure (semiconductor device) intended to form a required circuit block by incorporating and stacking a plurality of chips, for example, typified by System Block Module manufactured by Toshiba Corporation Semiconductor Company. In this semiconductor device, connection between upper and lower layers is established around chips. Accordingly, on the upper and lower surfaces of each package, top-and-bottom connecting pads are placed around the chip. The top-and-bottom connecting pads are used for connecting packages (chips) stacked on and under the relevant package (chip). Most of the top-and-bottom connecting pads are connected also within the relevant package. In such a semiconductor device, plated through holes have been typically used as means for connecting the top-and-bottom connecting pads within the package.
    [0008]For example, as described in Japanese unexamined Patent Publication (JPP) 2001-217337, technologies relating to the above-described known technology include the following technology: multilayer stacking can be realized by burying and mounting a semiconductor chip in a package, and providing external connection terminals on both surfaces of the package or exposing, from a solder resist layer, terminal formation portions (pad portions) of a wiring pattern to which external connection terminals are to be connected.
    [0009]As described above, in a known package structure (semiconductor device) adapted for the stacking of a plurality of chips using top-and-bottom connecting pads provided in a region around the chips, plated through holes have been utilized when the top-and-bottom connecting pads are connected within the package.
    [0010]However, plated through holes are often formed by drilling. Consequently, the diameters of the through holes become relatively large (approximately 250 to 300 μm in the state of the art), and there has been the disadvantage in that a larger area is accordingly required. Further, there are constraints on design (i.e., the degree of freedom of wiring is low), such as a technical difficulty of placing top-and-bottom connecting pads on plated through holes. Accordingly, the relevant pads must be formed at other positions, and an area required around a chip increases. This has become an obstacle to miniaturization.
    [0011]Essentially, one of major purposes in stacking chips is to enhance functionality by incorporating a larger number of functional elements (chips) into a smaller volume. However, the above-described problem becomes a serious obstacle to the accomplishment of this purpose. Namely, in a package (semiconductor device) containing a chip, a region around the chip is not a portion which exerts an essential function as the semiconductor device, but a portion used for simply connecting upper and lower stacked packages. Accordingly, in consideration of recent demands for smaller sizes, higher densities, and the like, of thin-type packages, it is more desirable that an area required around a chip is as small as possible.
    [0012]On the other hand, a conceivable method of coping with the above-described problems is as follows: after a chip is buried in resin, openings are formed at predetermined positions in a resin layer on the chip by laser processing, photolithography, or the like, to form via holes, and interconnections connected to pads of the chip through the via holes are formed. However, this method has a problem of the accuracy of opening positions when the via holes are formed on the chip. This becomes more pronounced as the sizes of via holes to be formed on the chip for electrical connection decreases and as the pitch decreases.
    [0013]SUMMARY OF THE INVENTION
    [0014]An object of the present invention is to provide a semiconductor device and a method of manufacturing the semiconductor device, in which when a semiconductor element (chip) is mounted in a package, miniaturization is realized and the degree of freedom of wiring is increased; in which necessity to form via holes for ensuring electrical connection to the chip is eliminated; in which a three-dimensional arrangement configuration of chips and connections therebetween can be easily realized as needed; and consequently which contributes to an enhancement of functionality.
    [0015]To attain the above object, according to one aspect of the present invention, there is provided a semiconductor device including: a wiring board; and at least one semiconductor element buried in the wiring board, wherein the wiring board has an insulating base material; a via hole formed in a region around the semiconductor element to pierce the insulating base material in a thickness direction is filled with a conductor; first and second conductor layers which are respectively connected to one end and another end of the conductor and which have required pattern shapes are formed; and protective films for respectively covering the insulating base material and the conductor layers are formed with first and second pad portions exposed, the first and second pad portions being respectively delimited in portions of the first and second conductor layers which correspond to the conductor, and wherein the semiconductor element is placed with flip-chip technology with at least some of electrode terminals electrically connected to the first conductor layer.
    [0016]In the semiconductor device according to this aspect, the semiconductor element (chip) is buried and mounted in the wiring board used as a package, and the via hole piercing the wiring board vertically (in the thickness direction) is formed in a region around the chip. This via hole can be formed to have a small diameter, for example, by laser processing, compared with a through hole formed by drilling as heretofore. This means that an area required around the chip can be relatively reduced, and contributes to a miniaturization of the package (semiconductor device).
    [0017]Also, since the via hole is filled with the conductor, the first and second pad portions (top-and-bottom connecting pads) can be placed thereon. Namely, compared with the case where a through hole is formed as heretofore and where top-and-bottom connecting pads cannot be placed thereon and must be formed at other positions, the degree of freedom of wiring can be increased. Further, since the relevant pads do not need to be formed at other positions, an area required around the chip can be accordingly reduced. This contributes to a further miniaturization of the package (semiconductor device).
    [0018]Moreover, since the semiconductor element (chip) is mounted with flip-chip technology to be electrically connected to the first conductor layer, the necessity to form via holes for ensuring electrical connection to the relevant chip (i.e., to form openings at predetermined positions in the insulating base material on the chip) is eliminated. Namely, hole-making process for the insulating base material by laser processing or the like is carried out only for a formation of the top-and-bottom connecting via hole in the region around the chip. Since the diameter of this via hole is sufficiently large compared with that of pads on the chip, the accuracy of an opening position can be relatively low when the via hole is formed.
    [0019]Furthermore, devices according to this aspect can be stacked in a multilayered manner by using as top-and-bottom connecting pads the first and second pad portions respectively exposed from both surfaces of the package (semiconductor device), and further, interposing external connection terminals as needed. Accordingly, it is possible to easily realize a three-dimensional arrangement configuration of chips and connections therebetween. This contributes to an enhancement of functionality.
    [0020]Also, according to another aspect of the present invention, there is provided a method of manufacturing a semiconductor device, including the steps of: forming a first conductor layer having a required pattern shape on one surface of a conductive base material, the first conductor layer extending within a semiconductor element mount region and having a first pad portion in a portion corresponding to a specific position around the semiconductor element mount region; mounting a semiconductor element with flip-chip technology to be electrically connected to the first conductor layer; forming an insulating base material to bury the semiconductor element; forming a via hole piercing the insulating base material to reach the first pad portion; filling a conductor into the via hole; forming a second conductor layer having a required pattern shape on the insulating base material, the second conductor layer being connected to the conductor filled in the via hole and having a second pad portion in a portion corresponding to the conductor; removing the conductive base material; and forming protective films respectively covering the insulating base material and the conductor layers with the first and second pad portions exposed.
    [0021]Also, according to still another aspect of the present invention, there is provided a method of manufacturing a semiconductor device, including the steps of: forming a first protective film on one surface of a conductive base material with a portion corresponding to a specific position around a semiconductor element mount region exposed; forming a first conductor layer having a required pattern shape on the first protective film and the conductive base material, the first conductor layer extending within the semiconductor element mount region and having a first pad portion in a portion corresponding to the specific position; mounting a semiconductor element with flip-chip technology to be electrically connected to the first conductor layer; forming an insulating base material to bury the semiconductor element; forming a via hole piercing the insulating base material to reach the first pad portion; filling a conductor into the via hole; forming a second conductor layer having a required pattern shape on the insulating base material, the second conductor layer being connected to the conductor filled in the via hole and having a second pad portion in a portion corresponding to the conductor; forming a second protective film covering the insulating base material and the second conductor layer with the second pad portion exposed; and removing the conductive base material.
    [0022]BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a cross-sectional view showing the structure of a semiconductor device according to a first embodiment of the present invention; FIGS. 2A to 2F are cross-sectional views showing manufacturing steps for the semiconductor device of FIG. 1 ; FIGS. 3A to 3E are cross-sectional views showing manufacturing steps subsequent to the manufacturing steps of FIGS. 2A to 2F ; FIG. 4 is a cross-sectional view showing the structure of a semiconductor device according to a second embodiment of the present invention; FIGS. 5A to 5F are cross-sectional views showing manufacturing steps for the semiconductor device of FIG. 4 ; FIGS. 6A to 6E are cross-sectional views showing manufacturing steps subsequent to the manufacturing steps of FIGS. 5A to 5F ; FIG. 7 is a cross-sectional view showing the structure of a semiconductor device according to a third embodiment of the present invention; FIGS. 8A to 8F are cross-sectional views showing manufacturing steps for the semiconductor device of FIG. 7 ; FIGS. 9A to 9E are cross-sectional views showing manufacturing steps subsequent to the manufacturing steps of FIGS. 8A to 8F ; FIG. 10 is a cross-sectional view showing the structure of a semiconductor device according to a fourth embodiment of the present invention; FIGS. 11A to 11F are cross-sectional views showing manufacturing steps for the semiconductor device of FIG. 10 ; FIGS. 12A to 12E are cross-sectional views showing manufacturing steps subsequent to the manufacturing steps of FIGS. 11A to 11F ; FIG. 13 is a cross-sectional view showing the structure of a semiconductor device according to a fifth embodiment of the present invention; FIG. 14 is a cross-sectional view showing the structure of a semiconductor device according to a sixth embodiment of the present invention; FIG. 15 is a cross-sectional view showing the structure of a semiconductor device according to a seventh embodiment of the present invention; FIG. 16 is a cross-sectional view showing the structure of a semiconductor device according to an eighth embodiment of the present invention; and FIG. 17 is a cross-sectional view showing the structure of a semiconductor device according to a ninth embodiment of the present invention.
    [0023]DESCRIPTION OF THE PREFERRED EMBODIMENTS
    [0024]FIG. 1 schematically shows a cross-sectional structure of a semiconductor device according to a first embodiment of the present invention.
    [0025]The semiconductor device 10 according to this embodiment includes a wiring board 20 used as a package, and a semiconductor element (silicon (Si) chip) 40 buried in this package (wiring board) 20 . In the illustrated example, one semiconductor chip 40 is buried in one package. However, two or more semiconductor chips 40 may be appropriately buried therein depending on functions required for the present device 10 .
    [0026]In the package (wiring board) 20 , reference numeral 21 denotes an insulating base material (e.g., a resin layer made of epoxy resin or the like) which serves as a base for the wiring board. In this resin layer 21 , via holes VH piercing the resin layer 21 in the thickness direction are formed in a region around the semiconductor chip 40 . These via holes VH are filled with conductors 22 (e.g., metal such as copper (Cu)). One end (lower surface in the illustrated example) of the conductor 22 is connected to a conductor layer 23 which is formed into a required pattern shape and which is made of conductive material (e.g., palladium (Pd), nickel (Ni), or gold (Au)). The portion of this conductor layer 23 which corresponds to the conductor 22 is delimited as a pad portion 23 P and exposed at one surface (lower surface) of the wiring board 20 . On the other hand, the other end (upper surface) of the conductor 22 is connected to a conductor layer 24 which is formed into a required pattern shape on the resin layer 21 and which is made of conductive material (e.g., Cu, Ni, or Au). The portion of this conductor layer 24 which corresponds to the conductor 22 is delimited as a pad portion 24 P. Together with the lower pad portion 23 P, the pad portion 24 P is also formed to have a diameter (approximately 150 μm) slightly larger than that (approximately 100 μm) of the via hole VH. On the pad portion 24 P, a conductor layer 25 (Ni/Au layer) is formed by Ni/Au plating as needed. Furthermore, protective films 26 and 27 (e.g., solder resist layers) are formed on both surfaces of the resin layer 21 in such a manner that the entire surfaces are covered with the pad portions 23 P and the pad portions 24 P (Ni/Au layer 25 ) exposed, respectively. The lower protective film 26 is made of a solder resist layer having a two-layer structure as described later. In the drawings, the two-layer structure is indicated as 26 a and 26 b of the lower protective film 26 . Further, an external connection terminal 28 (e.g., solder bump) is bonded to the upper pad portion 24 P (Ni/Au layer 25 ).
    [0027]The external connection terminal 28 is provided in the illustrated example, but does not necessarily need to be provided. It is essential only that the pad portion 24 P (Ni/Au layer 25 ) is exposed from the solder resist layer 27 so that an external connection terminal can be bonded thereto when necessary. Further, the external connection terminal 28 is provided only on one surface (upper surface) of the package (wiring board) 20 in the illustrated example, but may be provided on both surfaces of the package (wiring board) 20 as needed. In this case, the external connection terminal 28 is also bonded to the lower pad portion 23 P. Alternatively, instead of providing the external connection terminal 28 on the upper pad portion 24 P (Ni/Au layer 25 ), the external connection terminal 28 may be provided only on the lower pad portion 23 P.
    [0028]On the other hand, the semiconductor chip 40 is mounted within the package (wiring board) 20 with flip-chip technology as shown in the drawing. Namely, the semiconductor chip 40 is connected by flip-chip bonding, via electrode terminals 41 (e.g., solder bumps or Au stud bumps) bonded onto pads thereof, to a conductor 42 (e.g., metal such as solder) which is filled in a specific position in the lower solder resist layer 26 , and further bonded to the solder resist layer 26 via underfill resin 43 which is filled in the space between the semiconductor chip 40 and the solder resist layer 26 . Here, the “specific position” in the solder resist layer 26 , means a position corresponding to the pad, which is located on the relevant chip, in a portion of the conductor layer 23 including the pad portion 23 P which extends within a chip mount region. Accordingly, at least some of the electrode terminals 41 of the semiconductor chip 40 are electrically communicated with the conductor layer 23 (pad portions 23 P) via the conductors 42 . Further, it is desirable that a semiconductor chip having a thickness as small as possible is used as the semiconductor chip 40 because the semiconductor chip 40 is mounted within the package (wiring board) 20 . In the state of the art, semiconductor chips having a thickness of approximately 50 to 100 μm have been provided. It is sufficiently technically possible to bury a semiconductor chip having a thickness in this range in the board. Accordingly, in this embodiment, a thin semiconductor chip having a thickness of approximately 50 μm is used as the semiconductor chip 40 .
    [0029]The semiconductor device 10 according to this embodiment has the following features: the necessity to form via holes (i.e., via holes piercing the resin layer 21 on the chip 40 ) for ensuring electrical connection to the chip 40 is eliminated by mounting the thin semiconductor chip 40 within the package (wiring board) 20 with flip-chip technology; the insides of the via holes VH formed around the chip 40 are filled with the conductors 22 so that top-and-bottom connecting pads (pad portions 23 P and 24 P) can be placed thereon; and furthermore that multilayer stacking can be realized using the top-and-bottom connecting pads as needed, as described later.
    [0030]Hereinafter, a method of manufacturing the semiconductor device 10 according to the first embodiment will be described with reference to FIGS. 2A to 3E which show manufacturing steps thereof in order.
    [0031]To begin with, in the first step ( FIG. 2A ), copper foil 35 is prepared as a conductive base material, and the conductor layer 23 having a required pattern shape is formed on one surface (upper surface in the example) of the copper foil 35 . Namely, as shown in the drawing, patterning is performed so that the conductor layer 23 extends within the chip mount region MR and that portions corresponding to specific positions (positions where via holes described later are to be formed) around the chip mount region MR are delimited as the pad portions 23 P (having a diameter of approximately 150 μm). For example, a pattern having a required shape is formed of plating resist on the copper foil 35 (Cu), then the surface of the copper foil 35 is plated with nickel (Ni) as an underlying layer using the copper foil 35 as a power supplying layer, after that, it is plated with palladium (Pd) and further plated with gold (Au) as needed, then the plating resist is removed, thus the conductor layer 23 is formed.
    [0032]It is noted that, when the conductor layer 23 is formed, various passive elements (resistance element, inductance element, capacitance element) may be formed by a thin film process.
    [0033]In the next step ( FIG. 2B ), a solder resist layer 26 is formed to cover the conductor layer 23 and the copper foil 35 with a specific portion of the conductor layer 23 exposed. Here, the “specific portion” is equivalent to the aforementioned “specific position”, i.e., the position corresponding to the pad on a chip to be mounted, in the portion of the conductor layer 23 including the pad portion 23 P which extends within the chip mount region MR. For example, photosensitive solder resist is applied to the entire surface of the conductor layer 23 and the copper foil 35 , then exposure and development (patterning of solder resist) are performed in accordance with the shape of the above-described “specific portion” to form an opening (opening portion OP) in the portion of the solder resist layer which corresponds to the region of the specific portion. Thus, the specific portion of the conductor layer 23 is exposed, and the other portion of the conductor layer 23 is covered with the solder resist layer 26 a . This solder resist layer 26 a constitutes part (one layer of a solder resist layer) of the protective film 26 shown in FIG. 1 .
    [0034]In the next step ( FIG. 2C ), the opening portion OP of the solder resist layer 26 is filled with the conductor 42 . For example, solder paste is filled into the opening portion OP, or electrolytic solder plating is performed using the copper foil 35 as a power supplying layer, thus filling the opening portion OP.
    [0035]In the next step ( FIG. 2D ), the flip-chip bonding of the thin semiconductor chip 40 having a thickness of approximately 50 μm is performed using solder bumps, Au stud bumps, or the like (electrode terminals 41 ) in accordance with the positions of the conductors 42 in the chip mount region. Furthermore, the underfill resin 43 is filled into the space between the chip 40 and the solder resist layer 26 and cured, thus bonding the chip 40 to the solder resist layer 26 . Alternatively, instead of the underfill resin 43 , non-conductive paste (NCP) may be applied or non-conductive film (NCF) may be attached in advance so that the non-conductive paste or film is formed into a shape equivalent to that of the underfill resin 43 simultaneously with flip-chip bonding.
    [0036]In the next step ( FIG. 2E ), the resin layer 21 is formed on the solder resist layer 26 in such a manner that the semiconductor chip 40 is buried. For example, the resin layer 21 is formed using thermosetting resin, such as epoxy resin to be used as interlayer insulating material when a build-up printed circuit board is manufactured. Alternatively, instead of epoxy resin, polyimide resin may be used. The resin layer 21 functions as an insulating base material for the package (wiring board) 20 .
    [0037]In the next step ( FIG. 2F ), the via holes VH reaching the pad portions 23 P are formed at specific positions (positions corresponding to the portions on the conductor layer 23 in which the pad portions 23 P are delimited) around the chip mount region in the resin layer 21 . For example, the via holes VH having small diameters (approximately 100 μm) can be easily formed by removing the corresponding portions of the resin layer 21 using a CO 2 laser, an excimer laser, or the like.
    [0038]In the next step ( FIG. 3A ), the via holes VH formed around the chip are filled with the conductors 22 . For example, conductive paste containing metal, such as copper (Cu), is filled into the via holes VH, or electrolytic Cu plating is performed using the copper foil 35 as a power supplying layer, thus filling the via holes VH.
    [0039]In the next step ( FIG. 3B ), the conductor layer 24 having a required pattern shape is formed on the resin layer 21 to be connected to the conductors 22 which is filled in the via holes VH around the chip. At this time, the portions of the conductor layer 24 which correspond to the conductors 22 are delimited as the pad portions 24 P (having a diameter of approximately 150 μm). In the example, only the pad portions 24 P are shown. Specifically, a thin metal film is formed on the entire surface of the resin layer 21 by sputtering, electroless plating, or the like, and a pattern (pad portions 24 P) is formed by a subtractive method, a semi-additive method, or the like, using the thin metal film as a seed. For example, the entire surface of the resin layer 21 is made into a catalyst, electroless Cu plating is performed to have a thickness of approximately 3 μm (formation of the thin metal film), then a plating pattern is formed of plating resist, then, the surface of the thin metal film is electrolytically plated with Cu by pattern plating using the thin metal film as a power supplying layer, then the plating resist is removed, and thereafter unnecessary Cu is etched using the pattern made by electrolytic Cu plating as a mask, thus a Cu pattern (pad portions 24 P) is formed.
    [0040]Furthermore, the pad portions 24 P are plated with Ni/Au as needed (formation of the Ni/Au layer 25 ). This is intended to improve the adhesiveness to the conductor layer (pad portions) when solder bonding is performed in a later step.
    [0041]In the next step ( FIG. 3C ), the copper foil 35 used as a conductive base material is removed by wet etching. In this case, in order to prevent the pad portions 24 P (Cu) and the Ni/Au layer 25 formed on the resin layer 21 from being subjected to a chemical solution for wet etching, first, a protective film of etching resist or the like is formed on the surface on which the pad portions 24 P are formed, and then the protective film is removed after the copper foil 35 has been removed. Further, for the chemical solution for wet etching, a chemical solution which dissolves only the copper foil 35 but does not dissolve the conductor layer 23 (Ni/Pd/Au) is appropriately selected and used.
    [0042]In the next step ( FIG. 3D ), the solder resist layer 27 is formed to cover the resin layer 21 in such a manner that the pad portions 24 P formed on the upper surface are exposed, and a solder resist layer 26 (the rest of the portion of the protective film 26 ) is formed to cover the conductor layer 23 and the solder resist layer 26 (part of the protective film 26 shown in FIG.1 ) in such a manner that the pad portions 23 P formed on the lower surface are exposed. For example photosensitive solder resist is applied to the entire surface of the resin layer 21 , the conductor layers 23 and 24 , and the solder resist layer 26 (part of the protective film 26 shown in FIG. 1 ), and exposure and development are performed in accordance with the shapes of the pad portions 23 P and 24 P (patterning of the solder resist), whereby openings in the portions of the solder resist layer which correspond to the regions of the pad portions are formed. Thus, the pad portions 23 P and 24 P are exposed, and the other portions are covered with the solder resist layers 26 and 27 . With the forming of the solder resist layer 26 (the rest of the portion of the protective film 26 ), the conductor layer 23 is sandwiched between an inner-side portion of the protective film 26 (formed in the step shown in FIG. 2B ) and the outer-side portion of the protective film 26 (formed in the step shown FIG. 3D ).
    [0043]In the final step ( FIG. 3E ), the solder bumps 28 as external connection terminals are formed on the pad portions 24 P (Cu) exposed from the upper solder resist layer 27 . These solder bumps 28 can be formed, for example, by plating. Alternatively, the following method may be adopted: after flux is applied to the pad portions 24 P, solder balls are placed thereon, or solder paste is supplied thereto by printing, followed by the solder balls or the solder paste being made into bumps by reflow at a temperature of approximately 240° C. to 260° C. In this case, for after treatment, the surface is cleaned to remove the flux. In this way, the semiconductor device 10 ( FIG. 1 ) according to the first embodiment is manufactured.
    [0044]As described above, according to the first embodiment ( FIGS. 1 to 3E ), the semiconductor chip 40 is buried in the wiring board 20 used as a package, and the via holes VH are formed at specific positions around the chip by laser processing. Accordingly, the diameter of the individual via hole VH can be made small compared with the through hole formed by drilling as heretofore. Incidentally, in the state of the art, the diameter of the through hole is approximately 250 to 300 μm, while, in this embodiment, the diameter of the via hole VH can be made as small as approximately 100 μm. Thus, an area required around the semiconductor chip 40 becomes relatively small. Accordingly, the package 20 (semiconductor device 10 ) can be miniaturized.
    [0045]Also, since the via hole VH is filled with the conductor 22 , the pad portions 23 P and 24 P (top-and-bottom connecting pads) can be placed on the conductor 22 . In other words, the degree of freedom of wiring can be increased compared with the following case: plated through holes are formed as heretofore, and therefore top-and-bottom connecting pads cannot be placed thereon and must be formed at other positions. In addition, since the relevant pads do not need to be formed at other positions, an area required around the semiconductor chip 40 can be accordingly reduced. This contributes to a further miniaturization of the package 20 (semiconductor device 10 ).
    [0046]Moreover, the semiconductor chip 40 is connected to the conductors 42 which are filled in specific positions in the solder resist layer 26 by flip-chip bonding, and the conductors 42 are connected to the top-and-bottom connecting conductors 22 via the conductor layer 23 (pad portions 23 P). Accordingly, the necessity to form via holes for ensuring electrical connection to the relevant chip (i.e., to form openings at predetermined positions in the resin layer 21 on the chip 40 ) is eliminated. Namely, the hole-making process for the resin layer 21 by laser processing is carried out only for the formation of the top-and-bottom connecting via holes VH in the region around the chip. Since the diameters of such via holes are sufficiently large compared with those of the pads on the chip, thee accuracy of laser processing in positioning can be relatively low when the relevant via holes are formed.
    [0047]Moreover, packages according to this embodiment can be stacked in a multilayered manner as needed, as described later, by using the pad portions 23 P and 24 P exposed from the package 20 (semiconductor device 10 ) as top-and-bottom connecting pads or by interposing the external connection terminals (solder bumps 28 ) bonded to the tops of the pad portions 24 P. Accordingly, a three-dimensional arrangement configuration of semiconductor chips 40 and connections therebetween can be easily realized. This contributes to an enhancement of functionality of the semiconductor device.
    [0048]Furthermore, although the external connection terminals (solder bumps 28 ) do not necessarily need to be provided as described above, the provision of the external connection terminals has the following advantage. Specifically, since the formation of the external connection terminals (solder bumps 28 ) in the step of FIG. 3E makes it possible to conduct tests of functions, operations, and the like, of the package 20 (semiconductor device 10 ) in which the semiconductor chip 40 is buried, the relevant package can be rejected as a defective package at this stage if the relevant package does not pass the tests. Namely, only non-defective packages (semiconductor devices) can be picked up. This makes it possible to increase a yield on a product (semiconductor device) basis when non-defective packages are stacked in a multilayer structure to be modularized as described later.
    [0049]FIG. 4 schematically shows a cross-sectional structure of a semiconductor device according to a second embodiment of the present invention.
    [0050]In this embodiment, similar to the first embodiment ( FIG. 1 ), the semiconductor device 10 a includes a wiring board 20 a used as a package, and the semiconductor chip 40 buried in this package (wiring board) 20 a . The package (wiring board) 20 a in this embodiment differs from the package (wiring board) 20 in the first embodiment in the following points: a lower protective film 29 has a two-layer structure including an insulating layer Li on an exposed side and a solder resist layer L 2 on an internal layer side; and the portions (pad portions 30 P) of the conductor layer 30 which correspond to the conductors 22 are exposed, while the conductor layer 30 is electrically connected to the electrode terminals 41 of the chip 40 , to one surface (lower surface) of the wiring board 20 a via the conductor layer 23 . Other components and functions thereof are the same as those of the first embodiment, and thus the explanation thereof is omitted.
    [0051]Further, in a method of manufacturing the semiconductor device 10 a of this embodiment, some of manufacturing steps thereof are also different because of the features of the above-described constitution. Namely, the manufacturing method ( FIGS. 5A to 6E ) according to this embodiment differs from the manufacturing method ( FIGS. 2A to 3E ) according to the first embodiment in the following points: instead of the step of FIG. 2A , the insulating layer Li (first protective film) is formed on one surface of the copper foil 35 in such a manner that portions corresponding to specific positions around the chip mount region MR are exposed (step of FIG. 5A ); and furthermore, after the conductor layer 23 is formed in portions corresponding to the above-described specific positions, the conductor layer 30 having a required pattern shape is formed on the conductor layer 23 and the insulating layer L 1 so as to extend within the chip mount region MR and to have the pad portions 30 P on the conductor layer 23 (step of FIG. 5B ). Where the conductor layer 30 is formed, various passive elements (resistance element, inductance element, capacitance element) may be formed by a thin film process similarly to the case of the first embodiment (step of FIG. 2A ). Other steps are basically the same as in the case of the first embodiment, and thus the explanation thereof is omitted.
    [0052]Note, in the manufacturing method (refer to FIGS. 5A to 6E ) according to this second embodiment, unlike the case of the first embodiment, after the solder resist layer 27 has been formed in such a manner that the pad portions 24 P (Ni/Au layer 25 ) are exposed, and the solder bumps 28 have been formed on the pad portions 24 P (steps of FIGS. 6C and 6D ), then the copper foil 35 is removed (step of FIG. 6E ). In this case, if the order in which the formation of the solder resist layer 27 , the formation of the solder bumps 28 , and the removal of the copper foil 35 are performed is reversed similarly to the first embodiment, the external connection terminals (solder bumps 28 ) can be selectively bonded to both the upper pad portions 24 P (Ni/Au layer 25 ) and the lower pad portions 30 P (conductor layer 23 ).
    [0053]This second embodiment ( FIGS. 4 to 6E ) has effects similar to those of the first embodiment because the second embodiment has substantially the same constitution as the first embodiment.
    [0054]FIG. 7 schematically shows a cross-sectional structure of a semiconductor device according to a third embodiment of the present invention.
    [0055]In this embodiment, similar to the second embodiment ( FIG. 4 ), the semiconductor device 10 b includes a wiring board 20 b used as a package, and the semiconductor chip 40 buried in this package (wiring board) 20 b . The package (wiring board) 20 b in this embodiment differs from the package (wiring board) 20 a in the second embodiment in the following points: heat spreading via holes (thermal vias) TH are formed in the resin layer 21 to communicate with the surface of the semiconductor chip 40 which is opposite to the surface having the electrode terminals 41 formed thereon; and the thermal vias TH are filled with the conductors 22 as thermally conductive bodies, and furthermore, the pad portions 24 P (Ni/Au layer 25 ) on the conductors 22 are exposed from the solder resist layer 27 or covered with the exposed solder bumps 31 as thermally conductive bodies. Other components and functions thereof are basically the same as in the case of the second embodiment, and thus the explanation thereof is omitted.
    [0056]Further, in a method of manufacturing the semiconductor device 10 b of this embodiment, some of manufacturing steps thereof are also different because of the features of the above-described constitution. Namely, the manufacturing method ( FIGS. 8A to 9E ) according to this embodiment differs from the manufacturing method (refer to FIGS. 5A to 6E ) according to the second embodiment in the following points: when the via holes VH which pierce the resin layer 21 to reach the pad portions 30 P are formed in the step of FIG. 8F , the thermal vias TH are formed to reach the surface of the semiconductor chip 40 which is opposite to the surface having the electrode terminals 41 formed thereon; when the via holes VH are filled with the conductors 22 in the step of FIG. 9A , the thermal vias TH are filled with the conductors 22 as thermally conductive bodies; and when the solder resist layer 27 is formed in the step of FIG. 9C , the pad portions 24 P (Ni/Au layer 25 ) on the thermal vias TH, together with the pad portions 24 P (Ni/Au layer 25 ) on the via holes VH, are exposed. Incidentally, where the conductor layer 30 is formed in the step of FIG. 8B , various passive elements (resistance element, inductance element, capacitance element) may be formed by a thin film process similarly to the case of the second embodiment (step of FIG. 5B ). Other steps are basically the same as in the case of the second embodiment, and thus the explanation thereof is omitted.
    [0057]According to this third embodiment ( FIGS. 7 to 9E ), in addition to various advantages obtained in the second embodiment, when packages 20 b (semiconductor devices 10 b ) according to this embodiment are stacked in a multilayer structure to be modularized, heat generated in each chip 40 in the device can be spread to the outside via the solder bumps 31 (thermally conductive bodies), based on the features of the above-described constitution.
    [0058]Incidentally, in this third embodiment, a process (formation of the thermal vias TH) of forming openings at predetermined positions in the resin layer 21 on the chip 40 is performed. These thermal vias TH are via holes for heat spreading, not via holes for ensuring electrical connection to the relevant chip. Accordingly, the accuracy of laser processing in positioning may be relatively low when the thermal vias TH are formed.
    [0059]FIG. 10 schematically shows a cross-sectional structure of a semiconductor device according to a fourth embodiment of the present invention.
    [0060]In this embodiment, similar to the second embodiment ( FIG. 4 ), the semiconductor device 10 c includes a wiring board 20 c used as a package, and the semiconductor chip 40 buried in this package (wiring board) 20 c . The package (wiring board) 20 c in this embodiment differs from the package (wiring board) 20 a in the second embodiment in the following points: the portions (pad portions 30 P) of a conductor layer 30 c which correspond to the conductors 22 are exposed, while the conductor layer 30 c is electrically connected to the electrode terminals 41 of the chip 40 , to one surface (lower surface) of the wiring board 20 c via a conductor layer 23 ; and the pad portions 30 P (conductor layer 23 c ) protrude from the exposed surface of the protective film 29 . Other components and functions thereof are the same as in the case of the second embodiment, and-thus the explanation thereof is omitted.
    [0061]Further, in a method of manufacturing the semiconductor device 10 c of this embodiment, some of manufacturing steps thereof are also different because of the features of the above-described constitution. Namely, the manufacturing method ( FIGS. 11A to 12E ) according to this embodiment differs from the manufacturing method ( FIGS. 5A to 6E ) according to the second embodiment in the following point: in the step of FIG. 11B , recessed portions RP are formed in portions (portions in which the pad portions 30 P are to be formed) corresponding to specific positions around the chip mount region MR by etching the copper foil 35 , and furthermore, the conductor layer 23 c is formed on the surfaces of the recessed portions RP. Since the recessed portions RP are thus formed in the portions in which the pad portions 30 P are to be formed, the pad portions 30 P (conductor layer 23 c ) protrude from the exposed surface of the protective film 29 (L 1 and L 2 ) when the copper foil 35 is removed in a later step ( FIG. 12E ). Incidentally, where the conductor layer 30 c is formed in the step of FIG. 11C , various passive elements (resistance element, inductance element, capacitance element) may be formed by a thin film process similarly to the case of the second embodiment (step of FIG. 5B ). Other steps are basically the same as in the case of the second embodiment, and thus the explanation thereof is omitted.
    [0062]According to this fourth embodiment (refer to FIGS. 10 to 12E ), in addition to various advantages obtained in the second embodiment, when packages 20 c (semiconductor devices 10 c ) according to this embodiment are stacked in a multilayer structure to be modularized, the amount of solder used for connections between the packages can be decreased because the pad portions 30 P (conductor layer 23 c ) protrude, based on the features of the above-described constitution.
    [0063]Further, in the steps of Figs. 11B and 1C , where the insides of the recessed portions RP are filled with solder by electrolytic solder plating, instead of forming the conductor layer 23 c in the recessed portions RP and further forming the pad portions 30 P on the conductor layer 23 c , solder bumps as external connection terminals of the semiconductor device 10 c can be finally constituted.
    [0064]FIGS. 13 to 16 schematically show cross-sectional structures of semiconductor devices according to fifth to eighth embodiments of the present invention, respectively.
    [0065]The semiconductor devices 50 , 50 a , 50 b , and 50 c ( FIGS. 13 , 14 , 15 , and 16 ) according to the fifth, sixth, seventh, and eighth embodiments each have a stacked structure in which semiconductor devices 10 , 10 a , 10 b , or 10 c ( FIGS. 1 , 4 , 7 , or 10 ) according to the first, second, third, or fourth embodiment are stacked in three layers to be modularized, respectively. In each of the semiconductor devices 50 , 50 a , 50 b , and 50 c , two vertically adjacent semiconductor devices 10 , 10 a , 10 b , or 10 c are electrically connected to each other via the top-and-bottom connecting pads (pad portions 23 P, 30 P, conductor layer 23 , 23 c ) of one semiconductor device and the external connection terminals (solder bumps 28 ) of the other, and bonded together using underfill resin 51 filling the space between both devices. Furthermore, in the semiconductor device 50 b ( FIG. 15 ), two vertically adjacent semiconductor devices 10 b are thermally coupled together via thermally conductive bodies (solder bumps 31 ).
    [0066]Further, in each of the semiconductor devices 50 , 50 a , and 50 b ( FIGS. 13 to 15 ) according to the fifth to seventh embodiments, in order to realize a stacked structure, the semiconductor device 10 , 10 a , or 10 b in each layer has the external connection terminals (solder bumps 28 ) provided on both surfaces thereof. Meanwhile, in the semiconductor device 50 c ( FIG. 16 ) according to the eighth embodiment, each of the semiconductor devices 10 c in the uppermost and middle layers has the external connection terminals (solder bumps 28 ) provided only on one surface (upper surface) thereof, and the semiconductor device 10 c in the lowest layer has the external connection terminals (solder bumps 28 , 28 c ) provided on both surfaces thereof. In this case, the amount of solder used for the lower solder bumps 28 c of the semiconductor device 10 c in the lowest layer is relatively small because the conductor layer 23 c protrudes in convex shapes.
    [0067]Further, in the semiconductor device 50 b ( FIG. 15 ) according to the seventh embodiment, it is desirable that the semiconductor device 10 b in which the chip 40 spreading the largest amount of heat is buried is provided in the uppermost layer in consideration of the direction of spread heat(direction from bottom to top) generated in the chips 40 buried in the stacked semiconductor devices 10 b.
    [0068]Incidentally, for each of the semiconductor devices 50 , 50 a , 50 b , and 50 c according to the fifth to eighth embodiments, the description has been made taking as an example the case where the semiconductor devices 10 , 10 a , 10 b , or 10 c according to the first to fourth embodiments are stacked in three layers to be a multilayer structure. However, it is a matter of course that the number of stacked layers is not limited to three. Namely, the number of stacked layers can be appropriately selected according to functions required for a semiconductor device having a modularized stacked structure.
    [0069]FIG. 17 schematically shows a cross-sectional structure of a semiconductor device according to a ninth embodiment of the present invention. In the semiconductor device 50 d of this embodiment, a radiating fin (radiator) 60 for effectively spreading heat generated in the chips 40 provided inside the relevant device to the outside is attached to the semiconductor device 50 b having the stacked structure shown in FIG. 15 . Namely, this radiating fin 60 is brought into contact with the solder bumps 31 (thermally conductive bodies) exposed from the semiconductor device 10 b in the uppermost layer to be bonded to the solder resist layer 27 of the relevant semiconductor device 10 b with adhesive 61 having high thermal conductivity. As the adhesive, for example, thermosetting resin, such as epoxy resin, is used. Alternatively, instead of adhesive, adhesive sheet (prepreg) can also be used. As the adhesive sheet (prepreg), a reinforcing member, such as a glass cloth, which has been immersed in thermosetting resin, such as epoxy resin or BT resin, to be brought into B stage state, is typically used.
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