• 学术搜索
  • 科研智能体
    • Research Labs
    • AI 阅读
    • AI 文库
    • 深度研究
    • 学者亮点
  • 学术资源
    • AI2000
    • 期刊/会议
    • 学者库
    • 学术API
    • 溯源树
    • 数据集
  • 知识沉淀
    • 学术空间
订阅小程序
旧版功能
aminer vip
开通会员低至0.73元/天
一次搞定AI科研
立即登录
  • English
    • 联系方式
    专

    Ku波段吸透一体的频率选择表面单元结构及表面结构

    1771221864A
    发明人
    刘健, 王佳仪, 蔡通, 王雪丁, 郑斌, 陈红胜
    受让人
    ZHEJIANG SEAPEROT MICROWAVE SCIENCE AND TECH LIMITED COMPANY, UNIV ZHEJIANG
    申请人
    瑞安市方圆聚氨酯有限公司
    申请号
    900442
    申请日
    2006-03-30
    公开(公告)号
    1771221864A
    公开(公告)日
    1984-05-13
    IPC分类号
    B28B001/14B28B007/00B22C009/10B22C001/18B22C001/20
    CPC分类号
    -
    优先权号
    202120171330
    优先权日
    2021-01-21
    摘要

    Provided herein are systems and methods for functionalizing a substrate. The method may comprise providing a substrate surface, wherein the substrate surface comprises a plurality of individually addressable locations, and exposing the substrate surface to a dose of organosilane vapor to generate a plurality of organosilane-functionalized locations on the substrate surface, wherein the plurality of organosilane-functionalized locations corresponds to at least a subset of the plurality of individually addressable locations. The dose of organosilane vapor may be provided at relatively low dose, in an example, at most about 1×1024molecules per m2.

    权利要求
    wherein “p” represents an integer of 1 to 3; R 11 represents a hydrocarbyl group having 1 to 20 carbon atoms and optionally having a heteroatom; two of the three substituents bonded to the sulfonium cation are optionally bonded each other to form a ring together with the sulfur atom to which the two substituents are bonded; R f represents a fluorine atom, a fluorine-atom-containing alkyl group, a fluorine-atom-containing alkoxy group, or a fluorine-atom-containing sulfide group, each group having 1 to 6 carbon atoms; “q” represents an integer of 1 to 4, and when q≥2, R f may be same as or different from each other; R ALU represents an acid-labile group formed together with the adjacent oxygen atom; “r” represents an integer of 1 to 4; R 12 represents a hydrocarbyl group having 1 to 20 carbon atoms and optionally having a heteroatom; “s” represents an integer of 0 to 4; “t” represents an integer of 0 to 2; q+r+s≤5 when t=0, q+r+s≤7 when t=1, and q+r+s≤9 when t=2; R f and —O-R ALU are bonded to adjacent carbon atoms; and X − represents a non-nucleophilic counterion having no polymerizable group.
    wherein in the formula (ALU-1), R 21 , R 22 , and R 23 each independently represent a hydrocarbyl group having 1 to 10 carbon atoms and optionally having a substituent; any two of R 21 , R 22 , and R 23 are optionally bonded each other to form a ring; “u” represents an integer of 0 or 1; in the formula (ALU-2), R 24 and R 25 each independently represent a hydrogen atom or a hydrocarbyl group having 1 to 10 carbon atoms and optionally having a substituent; R 26 represents a hydrocarbyl group having 1 to 20 carbon atoms, or R 26 is optionally bonded to R 24 or R 25 each other to form a heterocyclic group having 3 to 20 carbon atoms together with Xa and the carbon atom to which R 24 and R 25 are bonded; —CH 2 — contained in the hydrocarbyl group and the heterocyclic group is optionally substituted with —O— or —S—; X a represents an oxygen atom or a sulfur atom; “v” represents an integer of 0 or 1; and “*” represents a bond to the adjacent oxygen atom.
    3 . The sulfonium salt according to claim 1 , wherein in the formula (1), X − being the non-nucleophilic counterion having no polymerizable group represents a sulfonate anion, an imide anion, or a methide anion.
    4 . The sulfonium salt according to claim 2 , wherein in the formula (1), X − being the non-nucleophilic counterion having no polymerizable group represents a sulfonate anion, an imide anion, or a methide anion.
    5 . A photoacid generator, comprising the sulfonium salt according to claim 1 .
    6 . A resist composition, comprising the photoacid generator according to claim 5 .
    wherein R A each independently represents a hydrogen atom, a fluorine atom, a methyl group, or a trifluoromethyl group; Z A represents a single bond, a phenylene group, a naphthylene group, or (main chain)-C(═O)—O—Z A1 —; Z A1 represents a linear, branched, or cyclic alkanediyl group having 1 to 10 carbon atoms, a phenylene group or a naphthylene group, the alkanediyl group optionally having a hydroxy group, an ether bond, an ester bond, or a lactone ring; Z B represents a single bond or (main chain)-C(═O)—O—; X A and X B each independently represent an acid-labile group; R B represents a linear, branched, or cyclic monovalent hydrocarbon group having 1 to 20 carbon atoms and optionally having a heteroatom; and “n” represents an integer of 0 to 4.
    wherein R A and Z B represent the same as above; Y A represents a hydrogen atom or a polar group having one or more structures selected from a hydroxy group other than a phenolic hydroxy group, a cyano group, a carbonyl group, a carboxy group, an ether bond, an ester bond, a sulfonate ester bond, a sulfonamide bond, a carbonate bond, a lactone ring, a sultone ring, a sulfur atom, and a carboxylic anhydride; R b represents a linear, branched, or cyclic monovalent hydrocarbon group having 1 to 20 carbon atoms and optionally having a heteroatom; and “m” represents an integer of 1 to 4.
    wherein R A represents the same as above; Z 1 represents a single bond or a phenylene group; Z 2 represents a single bond, *—C(═O)—O—Z 21 —, *—C(═O)—NH—Z 21 —, or *—O—Z 21 —; Z 21 represents an aliphatic hydrocarbylene group having 1 to 6 carbon atoms, a phenylene group, or a divalent group obtained by combining these groups, Z 21 optionally having a carbonyl group, an ester bond, an ether bond, or a hydroxy group; Z 3 represents a single bond, a phenylene group, a naphthylene group, or *—C(═O)—O—Z 31 —; Z 31 represents an aliphatic hydrocarbylene group having 1 to 10 carbon atoms, a phenylene group or a naphthylene group, the aliphatic hydrocarbylene group optionally having a hydroxy group, an ether bond, an ester bond, or a lactone ring; Z 4 represents a single bond, a methylene group, or *—Z 41 —C(═O)—O—; Z 41 represents a hydrocarbylene group having 1 to 20 carbon atoms and optionally having a heteroatom, an ether bond, or an ester bond; Z 5 represents a single bond, a methylene group, an ethylene group, a phenylene group, a fluorinated phenylene group, a phenylene group substituted with a trifluoromethyl group, *—C(═O)—O—Z 51 —, *—C(═O)—N(H)—Z 51 —, or *—O—Z 51 —; Z 51 represents an aliphatic hydrocarbylene group having 1 to 6 carbon atoms, a phenylene group, a fluorinated phenylene group, or a phenylene group substituted with a trifluoromethyl group, and Z 51 optionally has a carbonyl group, an ester bond, an ether bond, or a hydroxy group; “*” represents an attachment point to a carbon atom in the main chain or to a group bonding to the main chain; R 21 ′ and R 22 ′ are optionally bonded each other to form a ring together with the sulfur atom to which R 21 ′ and R 22 ′ are bonded; L 1 represents a single bond, an ether bond, an ester bond, a carbonyl group, a sulfonate ester bond, a carbonate bond, or a carbamate bond; Rf 1 and Rf 2 each independently represent a fluorine atom or a fluorinated alkyl group having 1 to 6 carbon atoms; Rf 3 and Rf 4 each independently represent a hydrogen atom, a fluorine atom, or a fluorinated alkyl group having 1 to 6 carbon atoms; Rf 5 and Rf 6 each independently represent a hydrogen atom, a fluorine atom, or a fluorinated alkyl group having 1 to 6 carbon atoms; not all Rf 5 and Rf 6 simultaneously represent hydrogen atoms; M − represents a non-nucleophilic counterion; A + represents an onium cation; and “c” represents an integer of 0 to 3.
    10 . The resist composition according to claim 6 , further comprising an organic solvent.
    wherein R q1 represents a hydrogen atom or a monovalent hydrocarbon group having 1 to 40 carbon atoms and optionally having a heteroatom, R q1 excluding a group in which a hydrogen atom bonded to a carbon atom at an α-position of the sulfo group is substituted with a fluorine atom or a fluoroalkyl group; R q2 represents a hydrogen atom or a monovalent hydrocarbon group having 1 to 40 carbon atoms and optionally having a heteroatom; and Mq + represents an onium cation.
    12 . The resist composition according to claim 6 , further comprising a second photoacid generator.
    13 . The resist composition according to claim 6 , further comprising an amine compound.
    14 . The resist composition according to claim 6 , further comprising: a surfactant insoluble or hardly soluble in water and soluble in an alkaline developer; and/or a surfactant insoluble or hardly soluble in water and an alkaline developer.
    15 . A patterning process, comprising steps of: forming a resist film on a substrate using the resist composition according to claim 6 ; exposing the resist film to high energy ray; and developing the exposed resist film using a developer.
    16 . The patterning process according to claim 15 , wherein the high energy ray is KrF excimer laser light, ArF excimer laser light, electron beam, or extreme ultraviolet ray having a wavelength of 3 to 15 nm.
    说明书
    [0001]REFERENCE TO RELATED APPLICATIONS
    [0002]This application claims the benefit of the earlier filing date of U.S. Provisional Application Ser. No. 61/962,623 filed on Nov. 12, 2013.
    [0003]STATEMENT CONCERNING GOVERNMENT INTEREST
    [0004]None.
    [0005]BACKGROUND OF THE INVENTION
    [0006]1. Field of the Invention
    [0007]The present invention relates to a clamping support structure useful in simulating a necktie, and more particularly to a nested set of conical segments which capture the edges of variously colored fabric to simulate the appearance of a necktie knot of one selected texture and color that is then combined to appear as a knot forming part of a necktie comprising distinctly different textures and/or colors.
    [0008]2. Description of the Prior Art
    [0009]A common appearance of one's attire, personal ornamentation, or most frequently a necktie, are often adopted as identifying symbols, or distinctive markings, by various groups like fraternal organizations, sororities, youth organizations, student groups attending a particular school, and the like, in order to quickly distinguish their members by a unique and highly visible symbol. While sometimes used as uniforms, distinctly marked, articles of clothing are prone to progress towards our functional needs, leaving this distinguishing task to the last non-functional item, a necktie, which few have learned to properly tie, and even when its knotting is learned, leave limited options for combining visible texture and color combinations that are contrasted right at the edges of the knot.
    [0010]In the past various mechanisms have been proposed which in one way or another seek to assist those unfamiliar with in the forming of a proper necktie knot exemplified by the teachings of U.S. Pat. No. 5,416,926 to Koy, U.S. Pat. No. 5,953,755 to Barylski, U.S. Pat. No. 6,094,746 to Miller, and others; illustrate structures that simply simulate a knot, as in U.S. Pat. No. 6,691,319 to Simon, U.S. Pat. No. 6,920,642 to Dickens, and others; or reform the necktie knot in a manner where it remains permanently tied while still allowing the necktie to be put on and removed, as in U.S. Pat. No. 3,737,917 to Orr. Each of the foregoing, while suitable for the purposes intended, provide little or no convenient facility to combine various colors and textures in a single necktie with the contrasting combination edges aligned right at the edges of the knot, to form a crisp delineation between the several colors and textures forming a symbolically distinctive article of clothing that emphasize the familiar shape of a necktie by its contrasting alignments.
    [0011]A necktie knot shaped nested assembly that conveniently captures the edges of a cloth covering segment to create the appearance of a knot together with other fabric pieces shaped as the descending portion of the tie along with a neck strap is therefore extensively desired and it is one such assembly that is disclosed herein.
    [0012]SUMMARY OF THE INVENTION
    [0013]Accordingly, it is the general purpose and object of the present invention to provide a structure facilitating the assembly of various fabric pieces into a necktie by capturing the separate tie ends and the edges of a fabric piece forming the knot appearance between conformingly nested pieces to simulate a knotted necktie.
    [0014]Other and further objects of the invention shall become apparent upon the examination of the description that follows in conjunction with the illustrations appended.
    [0015]Briefly, these and other objects are accomplished within the present invention by providing a nested set of generally C-sectioned, longitudinally tapered interlocking conical segments or pieces between which both the end panels or straps of a necktie are captured together with the edges of a separate fabric panel covering the exterior piece to simulate the decorative aspects of a distinctly colored and textured necktie knot. The internally captured strap end portions of the tie may be joined together at a stiffened segment of a conforming planform that is receivable between the nested segments with the narrower strap then looped back to extend as an adjustable neck strap that is frictionally retained by the nested compression but nonetheless left sufficiently free to allow for a fitted adjustment around the wearer's neck.
    [0016]Preferably each of the tapered and nested pieces is formed of a bendable sheet metal structure like sheet aluminum which once assembled in their nested form are then each pierced by a common drilling through which a fastening pin of a broche or medal is then passed once the necktie is assembled. It will be appreciated that the nesting offset of this common opening that results from the thickness increase attributable to the captured tie and knot fabrics will also provide a clamping effect, thus insuring a secure component engagement while still allowing strap adjusting movement for a good fit.
    [0017]In this manner various color and texture combinations can be repeated to achieve a uniformly distinct necktie that can be conveniently assembled by those joining a group by way of an assembly facilitated by a minimal nested structure that is then fixed together by a pin that may also serve as an attachment for additional decorative items or insignia indicating tenure or rank.
    [0018]BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a perspective illustration, separated by parts, of the inventive necktie simulating assembly; FIG. 2 is a further perspective illustration of the inventive necktie simulating assembly shown in FIG. 1 depicting the receiving side of the exterior piece of a nested support structure; FIG. 3 is yet another perspective illustration of the inventive necktie simulating assembly in its completed form; and FIG. 4 is a sectional view taken along line 4 - 4 of FIG. 3 , illustrating the engaged components of the inventive necktie simulating assembly.
    [0019]DESCRIPTION OF THE PREFERRED EMBODIMENT
    [0020]As shown in FIGS. 1 through 4 , the inventive necktie simulating assembly generally designated by the numeral 10 comprises an outer and inner, generally tapered frustoconical panel segment or piece 11 - o and 11 - i each provided with rolled-over lateral edges LE-o and LE-i dimensioned to define a space or gap between them that is conformed for a substantially matching nested receipt of the inner piece 11 - i within the outer piece 11 - o . Preferably, each of the nested pieces 11 - o and 11 - i are formed by rolled bending of corresponding generally trapezoidal exterior and interior metal panels, or sheets, to define a hollow interior space of a generally tapered conical frustum with the edges LE-o and LE-i of each panel, when nested in their frustoconical shape, overlying each other to define an access gap into the enclosed space which, on its panel exterior, approximates the general shape of a well-formed necktie knot.
    [0021]In this form the nested combination of the inner and outer pieces is useful to grasp the peripheral edges 12 E of a generally trapezoidal fabric piece 12 of planform dimensions greater than the panel planform of the outer piece 11 - o where it remains captured between the outer piece and the inner piece 11 - i to cover the outer piece with a separate fabric covering that is distinct from the remaining parts of the tie to present the appearance of a distinctly appearing tie knot that is crisply distinguished from the rest of the tie. To achieve the full benefit of this visual appearance a differently colored and textured tie end TE and strap ST are then each stitched at their hidden portions to one side of a common trapezoidal fabric piece 14 with the strap ST then looped back onto the other side of piece 14 to form a loop when the piece captured by the inner piece 11 - i.
    [0022]It will be appreciated that the tapering nested fit of the inner piece 11 - i within the outer piece 11 - o will produce an increasing capturing force between them as the inner piece is advanced further into the outer piece. Thus a predictably secure capturing engagement retaining the covering cloth 12 edges 12 E, the fabric piece 12 and the tie end TE can be achieved by way the positioning of alignment drillings 15 - o and 15 - i respectively in the outer piece 11 - o and the inner piece 11 - i through which a common fastening pin 16 P of a broche or insignia 16 is inserted to be then secured by a securement clip 17 , thus aligning the desired depth of nested receipt and therefore the lavel of capturing retention. Of course, the off-center alignment of the strap ST assures that its adjustable function remains in tact, allowing for the adjustment convenience assuring a comfortable fit around the user's neck.
    [0023]In this manner a well defined color and texture combination of a necktie is assured which, in view of the generally fixed structure of the knot defining portion repeatably assures a well-formed knot of one selected texture and color that is then combined with a tie end of the desired distinct texture and color to properly distinguish a fraternal organization, a business enterprise and so on. Significantly, this same distinct appearance is always associated with a well-formed and neatly defined knot.
    [0024]Obviously many modifications and variations of the instant invention can be effected without departing from the spirit of the teachings herein. It is therefore intended that the scope of the invention be determined solely by the claims appended hereto.
    同族专利
    暂无同族专利