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ChemInformVolume 20, Issue 16 Reviews ChemInform Abstract: Nucleophilic Ring Opening and Closure Reactions in Saturated Heterocycles V. A. BOBYLEV, V. A. BOBYLEV NPO Gos. inst. prikladn khim., Leningrad 197198Search for more papers by this authorS. G. KOLDOBSKII, S. G. KOLDOBSKII NPO Gos. inst. prikladn khim., Leningrad 197198Search for more papers by this authorG. F. TERESHCHENKO, G. F. TERESHCHENKO NPO Gos. inst. prikladn khim., Leningrad 197198Search for more papers by this authorB. V. GIDASPOV, B. V. GIDASPOV NPO Gos. inst. prikladn khim., Leningrad 197198Search for more papers by this author V. A. BOBYLEV, V. A. BOBYLEV NPO Gos. inst. prikladn khim., Leningrad 197198Search for more papers by this authorS. G. KOLDOBSKII, S. G. KOLDOBSKII NPO Gos. inst. prikladn khim., Leningrad 197198Search for more papers by this authorG. F. TERESHCHENKO, G. F. TERESHCHENKO NPO Gos. inst. prikladn khim., Leningrad 197198Search for more papers by this authorB. V. GIDASPOV, B. V. GIDASPOV NPO Gos. inst. prikladn khim., Leningrad 197198Search for more papers by this author First published: April 18, 1989 https://doi.org/10.1002/chin.198916381Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat No abstract is available for this article. Volume20, Issue16April 18, 1989 RelatedInformation
Experimental and calculated data on the mechanism and principal kinetic characteristics of processes involving the opening of saturated heterorings by nucleophiles, as well as reactions involving ring closing that proceed with departure of a nucleophilic particle, are correlated.
ChemInformVolume 18, Issue 8 Physical Organic Chemistry ChemInform Abstract: Investigation of the Aziridine and Oxirane Amination Mechanism. Part 3. Quantum Chemical Study of Specific Solvation Effects. S. G. KOLDOBSKII, S. G. KOLDOBSKII Gos. inst. prikladnoi khimii, Leningrad 197198Search for more papers by this authorG. F. TERESHCHENKO, G. F. TERESHCHENKO Gos. inst. prikladnoi khimii, Leningrad 197198Search for more papers by this authorV. A. BOBYLEV, V. A. BOBYLEV Gos. inst. prikladnoi khimii, Leningrad 197198Search for more papers by this authorA. R. DALIN, A. R. DALIN Gos. inst. prikladnoi khimii, Leningrad 197198Search for more papers by this author S. G. KOLDOBSKII, S. G. KOLDOBSKII Gos. inst. prikladnoi khimii, Leningrad 197198Search for more papers by this authorG. F. TERESHCHENKO, G. F. TERESHCHENKO Gos. inst. prikladnoi khimii, Leningrad 197198Search for more papers by this authorV. A. BOBYLEV, V. A. BOBYLEV Gos. inst. prikladnoi khimii, Leningrad 197198Search for more papers by this authorA. R. DALIN, A. R. DALIN Gos. inst. prikladnoi khimii, Leningrad 197198Search for more papers by this author First published: February 24, 1987 https://doi.org/10.1002/chin.198708040AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat No abstract is available for this article. Volume18, Issue8February 24, 1987 RelatedInformation
ChemInformVolume 18, Issue 8 Physical Organic Chemistry ChemInform Abstract: Investigation of the Aziridine and Oxirane Amination Mechanism. Part 4. Quantum Chemical Study of the Influence of a Polar Solvent Medium. S. G. KOLDOBSKII, S. G. KOLDOBSKII Gos. inst. prikladnoi khimii, Leningrad 197198Search for more papers by this authorG. F. TERESHCHENKO, G. F. TERESHCHENKO Gos. inst. prikladnoi khimii, Leningrad 197198Search for more papers by this authorV. A. BOBYLEV, V. A. BOBYLEV Gos. inst. prikladnoi khimii, Leningrad 197198Search for more papers by this authorA. R. DALIN, A. R. DALIN Gos. inst. prikladnoi khimii, Leningrad 197198Search for more papers by this author S. G. KOLDOBSKII, S. G. KOLDOBSKII Gos. inst. prikladnoi khimii, Leningrad 197198Search for more papers by this authorG. F. TERESHCHENKO, G. F. TERESHCHENKO Gos. inst. prikladnoi khimii, Leningrad 197198Search for more papers by this authorV. A. BOBYLEV, V. A. BOBYLEV Gos. inst. prikladnoi khimii, Leningrad 197198Search for more papers by this authorA. R. DALIN, A. R. DALIN Gos. inst. prikladnoi khimii, Leningrad 197198Search for more papers by this author First published: February 24, 1987 https://doi.org/10.1002/chin.198708041AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat No abstract is available for this article. References S. G. KOLDOBSKII, G. F. TERESHCHENKO, V. A. BOBYLEV, A. R. DALIN, Investigation of the Aziridine and Oxirane Amination Mechanism. Part 4. Quantum Chemical Study of the Influence of a Polar Solvent Medium., Khim. Geterotsikl. Soedin., 1986, 1042. Web of Science®Google Scholar Volume18, Issue8February 24, 1987 ReferencesRelatedInformation
The kinetics of the reaction of 5-phenyltetrazole triethylammonium salt with methyl vinyl ketone in acetonitrile and DMFA were studied. At a concentration of approx. 2.5 x 10/sup -1/ M the 5-phenyltetrazole triethylammonium salt is associated, and an intimate ion pair, formed with participation of a hydrogen bond, enters into reaction with the methyl vinyl ketone. The controlling stage is the formation of the anionic intermediate, the subsequent protonation of which leads to the final reaction products. The PMR spectra were recorded on a Perkin-Elmer R-12 spectrometer at 60 MHz in acetone-d/sub 6/ with HMDS as internal standard.
The effect of nonspecific solvation on the mechanism of the amination of three-membered rings was investigated by the MINDO/3 quantum-chemical method and by the solvaton model.