The paper reports the results of SIMS and SEM-EDS study of rock-forming minerals from melt pockets in the central part of a spinel peridotite xenolith taken from Quaternary alkaline basalts of Sverre Volcano in the northwestern part of West Spitsbergen Island. Olivine and clinopyroxene are analyzed to trace changes related to the metasomatic interaction between spinel lherzolite and a carbonate melt with formation of corresponding secondary minerals and silicate glass. It is established that the metasomatic interaction of the carbonate melt with minerals of host spinel lherzolite is accompanied by partial recrystallization of olivine and clinopyroxene, or crystallization of the second generation of these minerals. Percolating carbonate melt caused significant changes in the major, trace, and rare-earth element composition of the considered minerals, thus placing constraints on the use of the composition of these minerals for calculation of P – T parameters, estimating equilibrium, and modeling petrological processes in mantle.
The paper presents the results of a study (LA-ICP-MS method) of spinel from the collection of mantle xenoliths of lherzolites (seven xenoliths) selected in quaternary alkaline basalts of the Sverre volcano, the Spitsbergen archipelago. The study of two large (more than 15 cm in diameter) xenoliths made it possible to study changes in the composition of minerals in the central, intermediate, and marginal parts of the samples of chromium diopside spinel lherzolites. The sinusoidal character of the REE distribution in spinels, which indicates the manifestation of mantle metasomatism, is established. The results obtained for the first time on the trace-element composition for spinels from mantle xenoliths in alkaline basalts of the Spitsbergen archipelago are supplemented by data on the geochemistry of spinels of mantle origin published in the world literature.