The kinetics of photodissociation of ferrocene in bisphenol A dicyanate oligomer is studied using photospectroscopy. Thermograms of bisphenol A dicyanate oligomer polymerization in the presence of photodissociated ferrocene are obtained. Kinetic calculations and analysis of the thermograms lead to the conclusion that systems based on bisphenol A dicyanate oligomer and ferrocene may find application in 3D printing.
The kinetics of processes related to the dissociation of ferrocene in bisphenol А dicyanate oligomer under UV light is studied. Using the kinetic data rate constants are calculated and assumption regarding the mechanism of photochemical reactions occurring in the system is made. The photodissociation of ferrocene under medium-wave UV irradiation becomes possible due to the presence of cyanate ester iminocarbamate derivatives in the oligomer mixture.
The kinetic studies of photodissociation of ferrocene in the oligomer of bisphenol A dicyanate were done using photospectroscopy. Thermograms of polymerization of the bisphenol A dicyanate oligomer in the presence of photodissociated ferrocene were also obtained. Based on kinetic calculations and analysis of thermograms, conclusion has been made regarding the possibility and promising use of a system based on the oligomer bisphenol A dicyanate and ferrocene for 3D printing.